Table 3 Metabolites composition of T. boudieri and T. claveryi analyzed via UPLC-MS.

Amino acids and carbohydrates

1

N, N′-Di-α-hexosyl-butanediamine

C₁₆H₃₂N₂O₁₀

4.4

342, 234

 + 

413.211

0.743

2

Choline Glutamate

C₁₀H₂₂N₂O₅

6.2

233, 216, 198

 + 

251.159

0.777

3

Eletefine

C₁₉H₁₉NO₅

 − 8.5

324, 306, 288

 + 

342.134

0.811

4

N-Methyl-L-glutamic acid

C₆H₁₁NO₄

5.4

146,127

 + 

162.076

0.849

5

N-Glucosyl arginine

C₁₂H₂₄N₄O₇

7.3

319, 175

 + 

337.172

0.856

6

Arginine

C₆H₁₄N₄O₂

5.5

158

 + 

175.118

0.859

7

Xylonic acid

C₅H₁₀O₆

1.9

147, 129, 87, 75

 + 

165.041

0.946

8

Unknown amino sugar

C₉H₁₇NO₇

5.5

234, 216, 170

 + 

 + 

252.108

0.955

9

Sucrose

C₁₂H₂₂O₁₁

 − 0.1

162

 + 

341.109

0.994

10

Fructosyl valine

C₁₁H₂₁NO₇

0.1

118, 262, 126

 + 

280.137

1.014

11

N-Fructosyl pyroglutamate

C₁₁H₁₇NO₈

 − 1.3

128, 170, 200, 243, 272

 + 

 + 

290.088

1.021

12

N-fructosyl isoleucine

C₁₂H₂₃NO₇

0.1

276, 258, 230, 212, 86

 + 

 + 

294.155

1.036

13

Pyroglutamic acid

C₅H₇NO₃

0.3

 + 

1,280,353

130.05

1.463

14

Unknown amino sugar

C₁₆H₂₃NO₁₀

 − 1.3

244, 287, 306

 + 

 + 

388.125

1.864

15

N-Fructosyl phenylalanine

C₁₅H₂₁NO₇

4.7

310, 292, 264, 178, 166

 + 

 + 

328.137

2.682

16

N-acyl homoserine lactone

C₉H₁₆NO₄

3.4

186, 168, 99

 + 

202.107

2.74

17

Unknown amino sugar

C₁₄H₂₁NO₉

 − 1.9

189, 273

 + 

346.111

3.168

18

Pipecolate

C₆H₁₀NO₂

3

113

 + 

128.071

3.275

19

Stachydrine

C₇H₁₄NO₂

3.8

 + 

144.102

3.911

20

N-Acetyl-L-leucine

C₈H₁₅NO₃

-4.7

130

 + 

172.099

5.232

21

N-Acetylaspartic acid

C₁₄H₂₅NO₅

 − 0.2

214

 + 

286.166

11.748

Alkaloids

22

Vincapyridine C

C₁₂H₁₆NO₄

4.4

220, 179

 + 

 + 

238.107

5.273

23

4-Hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl

C₉H₁₈NO₂

 − 0.1

85

 + 

172.133

6.202

24

Puniceusine F

C₁₄H₁₆NO₄

2.6

244, 216,192

 + 

262.107

6.38

25

Hyrtiosine A

C₁₀H₉NO₃

4.3

176, 164

 + 

192.066

6.418

26

Piperlongumine

C₁₇H₁₉NO₅

1.7

212.1056

 + 

316.119

318.134

6.578

27

augustine N-oxide

C₁₇H₂₀NO₅

3.1

288, 258, 242

 + 

318.134

8.918

28

Fabiocinine

C₁₅H₁₄NO₃

4.1

210, 178, 105

 + 

256.097

11.654

29

Tersone G

C₁₄H₁₂NO₂

2.8

208, 172, 148, 105

 + 

226.086

12.186

30

Norargemonine

C₂₀H₂₂NO₄

3.6

294, 266

 + 

340.153

13.641

31

2-methyl-6-(9-phenylnonyl) piperidine-3,4-diol

C₂₁H₃₆NO₂

3.3

236, 220

 + 

334.274

14.17

32

17,20-dihydroxybuxadine-M

C₂₅H₄₂NO₂

1.8

238, 222

 + 

388.321

15.838

Amides

33

Dodecanamide

C₁₂H₂₆NO

 − 1.4

 + 

200.201

14.79

34

Octadecenoic acid amide

C₁₈H₃₅NO

2

247, 212, 163, 97

 + 

282.279

17.6

Fatty acids/esters

35

Hydroxytetradecanedioic acid

C₁₄H₂₆O₅

 − 2

 + 

273.171

10.415

36

Octadecenedioic acid

C₁₈H₃₂O₄

 − 0.7

311, 293

 + 

 + 

311.222

313.237

11.467

37

Hydroxyoctadecanedioic acid

C₁₈H₃₄O₅

 − 0.1

229, 211

 + 

 + 

329.233

11.666

38

Dodecanedioic acid

C₁₂H₂₂O₄

0.3

229, 211, 167

 + 

229.145

11.979

39

Octadecenedioic acid

C₁₈H₃₃O₄

3.8

295, 277

 + 

313.236

12.129

40

Trihydroxy trioxo docosanoic acid

C₂₂H₃₇O₈

4.2

411, 393, 293

 + 

429.248

12.606

41

Unknown fatty acyl amide

C₂₃H₄₄NO₃

3

357, 340, 277

 + 

382.332

12.723

42

Hexadecanedioic acid

C₁₆H₃₀O₄

 − 0.7

 + 

285.207

13.137

43

Octadecanedioic acid

C₁₈H₃₄O₄

0.3

295, 277, 183, 129

 + 

 + 

313.238

13.528

44

Hydroxy-octadecanoic acid

C₁₈H₃₅O₄

3.3

279, 261, 243

 + 

 + 

315.253

13.569

45

Hydroxy-octadecenoic acid

C₁₈H₃₃O₃

3.1

261, 243

 + 

279.231

14.064

46

Octadecatetraenoic acid

C₁₈H₂₈O₂

3.3

231, 176, 163

 + 

277.215

14.181

47

Unknown oxylipid

C₂₂H₄₀O₇

 − 0.2

 + 

415.27

14.406

48

Hydroxy-octadecadienoic acid

C₁₈H₃₂O₃

 − 0.9

295, 277, 195

 + 

 + 

295.228

15.023

49

Hydroxy-octadecatrienoic acid

C₁₈H₃₀O₃

0.4

 + 

293.212

295.227

15.288

50

Hydroxyoctadecanoic acid

C₁₈H₃₆O₃

1.3

 + 

299.258

16.119

51

Oxo-octadecadienoic acid

C₁₈H₂₈O₃

0.8

275, 223, 205, 187

 + 

293.21

16.522

52

Octadecatrienoic acid

C₁₈H₃₀O₂

 − 0.5

261, 223, 209, 173

 + 

277.218

279.232

16.812

53

Hydroxyhexadecanoic acid

C₁₆H₃₂O₃

1

 + 

 + 

271.228

16.992

54

linoleoyl glycerol

C₂₁H₃₈O₄

1.8

337, 263, 245

 + 

 + 

355.284

16.962

55

Hexadecenoic acid

C₁₆H₃₀O₂

0.4

 + 

253.217

17.239

56

Linoleic acid

C₁₈H₃₂O₂

 − 0.1

263, 245

 + 

 + 

279.233

281.248

17.46

57

Hexadecanoic Acid

C₁₆H₃₂O₂

 − 0.4

229, 173

 + 

255.233

257.248

17.646

Sterols

58

Hydroxystigmast-4-en-

C₂₉H₄₈O₂

3.1

297, 233

 + 

429.372

15.852

3-one

59

dankasterone A

C₂₈H₄₀O₃

3.3

407, 297, 165

 + 

425.304

15.976

60

Matsutoic acid

C₁₈H₃₀O₃

4.4

277, 259, 198, 180

 + 

295.224

16.202

61

Unknown sterol

C₁₉H₃₀O₃

2.4

289, 251

 + 

307.227

16.367

62

Paxisterol

C₂₈H₄₂O₄

2.3

341

 + 

443.316

17.034

Phenolic compounds

63

Hydroquinone-glucose-O-hexoside

C₁₂H₁₅O₇

4.1

161, 109, 101

 + 

271.081

1.624

64

Scopoletin

C₁₀H₈O₄

3.7

 + 

191.034

10.757

65

Flavonol 3-O-petosyl hexoside

C₂₆H₂₈O₁₂

 − 5.7

487, 443

 + 

531.154

11.667

66

isomyrtucommulone B

C₂₄H₃₀O₆

2.8

281, 119

 + 

415.212

13.786

Miscellaneous

67

Malic acid

C₄H₆O₅

 − 1.5

115, 87,71, 87

 + 

 + 

133.014

1.011

68

Unknown hexose

C₆H₁₀O₆

 − 0.6

129, 99, 89, 85, 75

 + 

 + 

177.041

1.028

69

Citric acid

C₆H₈O₇

 − 0.6

129, 111, 87

 + 

191.02

1.028

70

Succinic acid

C₄H₆O₄

 − 0.8

117, 99, 73

 + 

117.019

1.555

71

Citramalic acid

C₅H₈O₅

3.2

147, 103, 87

 + 

147.029

1.597

72

isoquinoline-1,4-diol

C₁₀H₁₃NO₂

4.1

103, 89

 + 

162.055

3.327

73

Menisdaurin D

C₁₄H₂₀N13O₇

2.3

225, 180

 + 

314.123

3.543

74

Homotyrosine methyl ether

C₁₁H₁₅NO₃

4.2

192, 96

 + 

210.113

3.774

75

Dihydroxybenzenebutanoic acid O hexoside

C₁₆H₂₂O₉

5.3

313

 + 

357.117

4.677

76

Cinnamic acid

C₉H₈O₂

2.9

 + 

147.045

5.761

77

Unknown nitrogenous

C₁₂H₁₇NO₃

0.2

128, 89

 + 

 + 

224.128

6.99

78

Unknown aromatic

C₁₄H₁₀O₃

6.2

124

 + 

225.054

7.553

79

Unknown amino sugar

C₁₂H₁₉NO₆

4

144

 + 

272.113

7.567

80

Phenylacetic acid

C₈H₈O₂

1.3

 + 

135.041

7.639

81

unknown terpenoid

C₁₆H₁₈O₅

4.4

181, 163

 + 

291.123

7.765

82

1-(1-b-Glucopyranosyl)-1H-indole-3-carbaldehyde

C₁₅H₁₇NO₆

 − 8.7

289, 261

 + 

306.101

12.179

83

Amino-octadecene-triol

C₁₈H₃₈NO₃

4

298, 280

 + 

316.283

12.723

84

Unknown terpenoid

C₁₉H₂₅O₅

4.2

289, 247, 203

 + 

333.17

13.042

85

Nitrogenous lipid

C₁₈H₂₉NO₃

3

290, 210, 192

 + 

308.221

14.666

86

LysoDGTSA 16:0

C₂₆H₅₁NO₆

2.1

456, 236

 + 

474.377

15.593

87

unknown diterpene

C₂₀H₃₄O₂

1.8

277, 261, 243, 219, 205, 187, 173, 163, 109, 95

 + 

307.263

16.9