Table 1 Analytical and some physical data of the synthesized mixed ligand complexes.
Mixed ligand complexes | M.Wt Found. (Calcd) | Color (% yield) | Elemental analysis, Found (Calcd.)% | Molar conductance (Ω−1 mol−1cm2) | |||||
|---|---|---|---|---|---|---|---|---|---|
C | H | N | Cl | M | H2O | ||||
[FeL(bpy)]Cl3·H2O FeC27H22N4O2Cl3.H2O | 615.00 (614.72) | Dark red (95) | 52.81 (52.76) | 3.28 (3.94) | 9.54 (9.11) | 17.01 (17.30) | 8.97 (9.08) | 2.10 (2.00) | 280 |
[CoL(bpy)]Cl2·3H2O CoC27H22N4O2Cl2·3H2O | 621.00 (618.38) | Dark green (95) | 51.99 (52.44) | 4.48 (4.56) | 8.91 (9.06) | 11.21 (11.46) | 9.43 (9.52) | 8.70 (8.73) | 163 |
[CuL(bpy)]Cl2 CuC27H22N4O2Cl2 | 570.00 (568.95) | Faint green (96) | 56.91 (57.00) | 3.55 (3.90) | 9.37 (9.85) | 12.30 (12.46) | 11.01(11.15) | – | 143 |
[CdL(bpy)](NO3)2 CdC27H22N6O8 | 670.00 (670.92) | Cacao brown (82) | 47.68 (48.34) | 3.53 (3.31) | 12.75 (12.53) | – | 16.34 (16.75) | – | 176 |
