Table 2 Attributions of lipids found as differentials between obese and non-obese individuals according to diffusion-edited 1H-NMR data.
Nº | Fragment of the corresponding molecule | δ 1H identified (ppm) |
|---|---|---|
1 | –CH3 | 0.50–1.10 |
FA | 0.5–0.8 | |
Cholesterol esterified | 0.8–1.1 | |
2 | –(CH2)n– FA | 1.20–1.30 |
3 | –CO–CH2–CH2– Cholesterol and FA (TAG, Phospholipids) | 1.50–1.60 |
4 | –CH2–CH=CH– (Allylic) | 1.95–2.01 |
5 | O–CO–CH2– (FA) | 2.20–2.30 |
6 | –CH2–CO–O–R (sn3 + sn1) | 4.00–4.40 |
7 | –CH–CO–O–R (sn2) | 5.15–5.25 |
8 | –CH=CH– (olefinic, UFA) | 5.25–5.40 |
9 | –CH2–CH=CH– (UFA) | 2.01–2.07 |
10 | –OOC–CH2–CH2 (FA) | 2.33 |
11 | –CH=CH–CH2–CH=CH– | 2.67–2.76 |
12 | Glycerol in TAG (2′-CHOCO–) | 5.26 |
13 | PUFA (9-cis, 11-cis) H9, H12 (–CH=) | 5.40 |
14 | PUFA (10-cis, 12-cis) H10, H13 (–CH=) | 6.13 |
15 | PUFA (10-cis, 12-cis) H11 (–CH=) | 6.22 |
16 | PUFA (9-cis, 11-cis) H10, H11 (–CH=) | 6.22 |
17 | PUFA (10-cis, 12-cis) H11, H12 (–CH=) | 6.85 |
18 | Phospholipids | FA (CH3–, –CH2– and other PUFA) |
19 | Phosphatidylcholines | 3.18–3.21 (CH3)3N+); FA; (CH3–, –CH2– and other PUFA) |
20 | Phosphorylcholine | 3.21; 3.58; 4.17 |