Table 5 Thermodynamic parameters for the adsorption of inhibitor compounds in 1 M HCl on carbon steel surface.

From: Synthesis and applications of novel Schiff base derivatives as corrosion inhibitors and additives for improvement of reinforced concrete

Inhibitor

T(K)

Slope

Intercept

R2

Kads M–1

ΔGoads kJ/mol

ΔSoads J/mol.K

ΔHoads kJ/mol

DHSiMF

303

1.13430

0.00002

0.9999

49,881

 − 37.37

12.55

 − 7.90

313

1.27428

0.00002

0.9999

52,769

 − 37.51

12.15

323

1.45333

0.00002

0.9999

42,148

 − 36.94

10.91

333

1.70702

0.00003

0.9999

39,165

 − 36.76

9.23

DHSiB

303

1.17786

0.00004

0.99983

23,971

 − 35.52

84.76

 − 11.07

313

1.26304

0.00005

0.99977

20,102

 − 35.08

82.66

323

1.48153

0.00005

0.99990

19,800

 − 35.04

81.65

333

1.72407

0.00006

0.99988

15,495

 − 34.42

82.74