Table 4 Comparison of the results acquired for epoxidation of cyclooctene catalyzed by the IUST-1 catalyst with some previous reports.
Entry | Catalyst | Support | Oxidant | Condition(°C)/solvent | Epoxide Conv% | Refs. |
|---|---|---|---|---|---|---|
1 | PW12/MIL-101 | Cyclooctene | H2O2 | Reflux/CH3CN | 76 | |
2 | UiO-66-Mo(CO)3 | Cyclooctene | TBHP | Reflux/CH3CN | 98 | |
3 | Co-MOF-150-2 | Cyclooctene | C9H12O2 | Air/Reflux | 78.5 | |
4 | PW-MOFa | Cyclooctene | H2O2 | Reflux/CH3CN | 83.5 | |
5 | Mo@UiO-67 | Cyclooctene | TBHP | Reflux/ CH2Cl2 | 100 | |
6 | (THA)2[W2 O3(O2)4] | Cyclooctene | H2O2 | Reflux/ CH3CN | 100 | |
7 | TMU-16-NH2 | Cyclooctene | TBHP | Reflux/CHCl3 | 83 | |
8 | UiO-66-NH2-SA-Mo | Cyclooctene | TBHP | Reflux/CH2CH2Cl2 | 97 | |
9 | CoPMA@UiO-bpy | Cyclooctene | H2O2 | Reflux/CH3CN | 91 | |
10 | IUST-1 | Cyclooctene | TBHP | Reflux/CCl4 | 99.8 | This work |
