Table 3 Kinetic study model fitting parameters.
Kinetic model | Kinetic equation | Model parameters | Values |
|---|---|---|---|
Pseudo first order | \({q}_{t}= {q}_{e} (1- {e}^{- {K}_{1}t}\)) qe is the adsorption capacity at equilibrium, k1 is the pseudo-first-order rate constant | K1 (min−1) | 0.12 |
qe (mg/g) | 43.48 | ||
R2 | 0.86 | ||
Pseudo second order | \({q}_{t}= \frac{{{q}_{e}}^{2} {K}_{2} t}{1+ {q}_{e} {K}_{2} t}\) k2 is the pseudo-second-order rate constant | K2 (g/(mg min)) | 0.004 |
qe (mg/g) | 46.6 | ||
R2 | 0.98 | ||
Mixed first and second order | \({q}_{t}= {q}_{e}\frac{1- {e}^{- K t}}{1- {f}_{2} {e}^{- K t}}\) f2 is the mixed 1 st, 2nd order coefficient, k is the adsorption rate constant | K (min−1) | 0.0022 |
qe (mg/g) | 46.33 | ||
f2 (g/(mg.min)) | 0.99 | ||
R2 | 0.98 | ||
Avrami model | \({q}_{t}= {q}_{e} \left(1-{\left[{e}^{- {K}_{av}t}\right]}^{{n}_{av}}\right)\) kav is the Avrami rate constant and nav is the model's component | Kav (min−1) | 43.48 |
nav (−) | 0.36 | ||
qe (mg/g) | 0.34 | ||
R2 | 0.86 | ||
Intraparticle diffusion | \({q}_{t}= {K}_{ip} \sqrt{t}+ {C}_{ip}\) Cip is intraparticle diffusion constant and kip is a measure of diffusion coefficient | kip | 1.66 |
Cip | 26.8 | ||
R2 | 0.76 |