Table 3 Kinetic study model fitting parameters.

From: Investigation of ternary Zn–Co–Fe layered double hydroxide as a multifunctional 2D layered adsorbent for moxifloxacin and antifungal disinfection

Kinetic model

Kinetic equation

Model parameters

Values

Pseudo first order

\({q}_{t}= {q}_{e} (1- {e}^{- {K}_{1}t}\))

qe is the adsorption capacity at equilibrium, k1 is the pseudo-first-order rate constant

K1 (min−1)

0.12

qe (mg/g)

43.48

R2

0.86

Pseudo second order

\({q}_{t}= \frac{{{q}_{e}}^{2} {K}_{2} t}{1+ {q}_{e} {K}_{2} t}\)

k2 is the pseudo-second-order rate constant

K2 (g/(mg min))

0.004

qe (mg/g)

46.6

R2

0.98

Mixed first and second order

\({q}_{t}= {q}_{e}\frac{1- {e}^{- K t}}{1- {f}_{2} {e}^{- K t}}\)

f2 is the mixed 1 st, 2nd order coefficient, k is the adsorption rate constant

K (min−1)

0.0022

qe (mg/g)

46.33

f2 (g/(mg.min))

0.99

R2

0.98

Avrami model

\({q}_{t}= {q}_{e} \left(1-{\left[{e}^{- {K}_{av}t}\right]}^{{n}_{av}}\right)\)

kav is the Avrami rate constant and nav is the model's component

Kav (min−1)

43.48

nav (−)

0.36

qe (mg/g)

0.34

R2

0.86

Intraparticle diffusion

\({q}_{t}= {K}_{ip} \sqrt{t}+ {C}_{ip}\)

Cip is intraparticle diffusion constant and kip is a measure of diffusion coefficient

kip

1.66

Cip

26.8

R2

0.76