Table 2 Table of included chemical reactions for \(\text {CO}_2\).
Reaction number | Description | Reaction | Rate | Unit | References |
|---|---|---|---|---|---|
\(R_1\) | Impact ionization | \(\text {e} + \text {CO}_2 \rightarrow \text {CO}_2^{+}+\text {e}+\text {e}\) | BOLSIG+ | m\(^{3}\)s\(^{-1}\) | |
\(R_2\) | Dissociation | \(\text {e}+\text {CO}_2 \rightarrow \text {CO} +\text {O}+ \text {e}\) | \(5\times 10^{-17}\) | m\(^{3}\)s\(^{-1}\) | |
\(R_3\) | Attachment | \(\text {e}+\text {CO}_2 \rightarrow \text {CO}+\text {O}^-\) | BOLSIG+ | m\(^{3}\)s\(^{-1}\) | |
\(R_4\) | Dissociation | \(\text {e}+\text {O}_3 \rightarrow \text {O} + \text {O}_2 + \text {e}\) | \(2\times 10^{-15}\) | m\(^{3}\)s\(^{-1}\) | |
\(R_5\) | Dissociation | \(\text {e}+\text {O}_2 \rightarrow \text {O}+\text {O}+\text {e}\) | \(2\times 10^{-15}\) | m\(^{3}\)s\(^{-1}\) | |
\(R_6\) | Dissociation | \(\text {e}+\text {O}_2 \rightarrow \text {O}+\text {O}^-\) | \(4\times 10^{-17}\) | m\(^{3}\)s\(^{-1}\) | |
\(R_7\) | Attachment | \(\text {e}+\text {O}_2+\text {M} \rightarrow \text {O}_2^- +\text {M}\) | \(3\times 10^{-42}\) | m\(^{6}\)s\(^{-1}\) | |
\(R_8\) | Ion-neutral reaction | \(\text {O}^-+\text {CO} \rightarrow \text {CO}_2+\text {e}\) | \(5.5\times 10^{-16}\) | m\(^{3}\)s\(^{-1}\) | |
\(R_9\) | Ion-neutral reaction | \(\text {O}^-+\text {O}_2 \rightarrow \text {O}_3 +\text {e}\) | \(1\times 10^{-18}\) | m\(^{3}\)s\(^{-1}\) | |
\(R_{10}\) | Ion-neutral reaction | \(\text {O}^- + \text {O}_3 \rightarrow \text {O}_2 + \text {O}_2 + \text {e}\) | \(3\times 10^{-16}\) | m\(^{3}\)s\(^{-1}\) | |
\(R_{11}\) | Electron-ion recombination | \(\text {e}+\text {CO}_2^+ \rightarrow \text {CO} + \text {O}\) | \(6.5\times 10^{-13}\) | m\(^{3}\)s\(^{-1}\) | |
\(R_{12}\) | Ion-ion recombination | \(\text {O}_2^- + \text {CO}_2^+ \rightarrow \text {CO} + \text {O}_2 + \text {O}\) | \(6\times 10^{-13}\) | m\(^{3}\)s\(^{-1}\) | |
\(R_{13}\) | Neutral reaction | \(\text {O}+\text {O}+\text {M} \rightarrow \text {O}_2 +\text {M}\) | \(1.04\times 10^{-45}\) | m\(^{6}\)s\(^{-1}\) | |
\(R_{14}\) | Neutral reaction | \(\text {O}+\text {O}_2+\text {M} \rightarrow \text {O}_3+\text {M}\) | \(4.42\times 10^{-46}\) | m\(^{6}\)s\(^{-1}\) | |
\(R_{15}\) | Neutral reaction | \(\text {O}+\text {O}_3 \rightarrow \text {O}_2 + \text {O}_2\) | \(7.56\times 10^{-18}\) | m\(^{3}\)s\(^{-1}\) | |
\(R_{16}\) | Neutral reaction | \(\text {O}+\text {CO}+\text {M} \rightarrow \text {CO}_2 + \text {M}\) | \(1.11\times 10^{-47}\) | m\(^{6}\)s\(^{-1}\) | |
\(R_{17}\) | Neutral reaction | \(\text {O}_3+\text {M} \rightarrow \text {O}_2 + \text {O} + \text {M}\) | \(1.16\times 10^{-32}\) | m\(^{6}\)s\(^{-1}\) |
