Table 2 The molar excess heat \({\gamma }_{{\text{col}}}{mQ}_{{\text{ann}}}\) and collision efficiency \({\gamma }_{{\text{col}}}\) newly observed.
Electrode type | Copper redox reaction without a diffuser \({\gamma }_{{\text{col}}}{mQ}_{{\text{ann}}}\) / kJ mol−1 | Copper redox reaction with a diffuser \({\gamma }_{{\text{col}}}{mQ}_{{\text{ann}}}\) / kJ mol−1 |
|---|---|---|
Single MHDE (m = 1) | 387 ± 165 | – |
(\({\gamma }_{{\text{col}}}\) = 0.679 ± 0.289) | – | |
Double bipolar MHDE (m = 2) | 702 ± 426 | 710 ± 144 |
(\({\gamma }_{col}\) = 0.616 ± 0.374) | (\({\gamma }_{{\text{col}}}\) = 0.623 ± 0.126) |