Table 10 The molecular weight data and an acid value of prepared PLLA samples.
Catalyst | Time (h) | Mw | [η] | Mv | AV |
|---|---|---|---|---|---|
MgO 75 mg | 10 | 3018 | 0.2121 | 3113 | 24.08 |
MgO 75 mg | 25 | 8480 | 0.2202 | 8747 | 28.05 |
MgO 50 mg | 25 | 1554 | 0.055 | 1603.6 | 56.1 |
SnCl2 (xylene only) | 25 | 10,099 | 0.2541 | 10,416.8 | 56.1 |
SnCl2 (Xylene: Decalin) | 25 | 24,874 | 0.5510 | 26,766 | 14 |
CaO | 25 | 4045 | 0.1200 | 4172.5 | 28.05 |
Al2O3 | 25 | 6557 | 0.1783 | 6763.4 | 37.4 |
Fe2O3 | 25 | 11,590 | 0.285 | 11,955 | 28.05 |
ZnCl2 | 25 | 11,051 | 0.265 | 10,974 | 14 |
Zn metal | 25 | 6754 | 0.1827 | 6967 | 14 |
ZnO | 25 | 11,356 | 0.4135 | 18,858 | 14 |
CaCl2 | 25 | 2979 | 0.0934 | 3073.3 | 42.08 |
Sb2O3 | 25 | 25,114 | 0.6482 | 32,625.3 | 14 |
As2O3 | 25 | 3823 | 0.1146 | 3944.1 | 97.6 |
TiO2 | 25 | 2788 | 0.0885 | 2876.3 | 105.2 |
Mg metal | 25 | 1111 | 0.0535 | 1550.7 | 168.3 |
Strontium chloride | 25 | 4004 | 0.119 | 4130 | 112.2 |
MgO/p-TSA (1:1) | 25 | 3803 | 0.1141 | 3923 | 80.1 |
MgO/p-TSA (2:1) | 25 | 6186 | 0.1700 | 6381 | 28.05 |
MgO/p-TSA (3:1) | 25 | 2227 | 0.0736 | 2298 | 35.06 |
MgO/MA (1:1) | 25 | 4166 | 0.1229 | 4298 | 30.05 |
MgO/MA (2:1) | 25 | 11,636 | 0.246 | 10,007 | 28.05 |
MgO/MA (3:1) | 25 | 5286 | 0.1495 | 5453 | 65.1 |
ZnO/p-TSA (1:1) | 25 | 1745 | 0.0602 | 1800 | 70.1 |
ZnO/p-TSA (2:1) | 25 | 11,239 | 0.2163 | 8559 | 14 |
ZnO/p-TSA (1:2) | 25 | 5948 | 0.1647 | 6136 | 14 |
ZnO/p-TSA (1:3) | 25 | 9006 | 0.2314 | 9290 | 42.08 |
ZnO/p-TSA (3:1) | 25 | 5033 | 0.1436 | 5192 | 33.0 |
ZnO/p-TSA (2:2) | 25 | 10,169 | 0.2556 | 10,489 | 28.05 |
ZnO/MA (2:2) | 25 | 595 | 0.0249 | 614.6 | 84.2 |
ZnO/MA (1:1) | 25 | 983 | 0.1308 | 1014 | 33.0 |
ZnO/MA (2:1) | 25 | 9208 | 0.3263 | 14,129 | 70.1 |
ZnO/MA (3:1) | 25 | 7823 | 0.2061 | 8069 | 37.4 |
ZnO/PA (2:2) | 25 | 3964 | 0.1180 | 4089 | 80.1 |
ZnO/PA (1:1) | 25 | 6403 | 0.1749 | 6605 | 112.2 |
ZnO/PA (2:1) | 25 | 2731 | 0.0869 | 2817 | 168.3 |
ZnO/PA (3:1) | 25 | 8297 | 0.2163 | 8559 | 74.8 |
ZnCl2/p-TSA | 25 | 2617 | 0.0840 | 2700 | 93.5 |
ZnCl2/MA | 25 | 1304 | 0.0580 | 1719 | 112.2 |
ZnCl2/PA | 25 | 1975 | 0.0667 | 2038 | 112.2 |
ZnO/ ZnCl2 (2:2) | 25 | 10,316 | 0.2701 | 11,218 | 61.1 |
ZnCl2/ZnO(2:2) | 25 | 2192 | 0.0726 | 2261.7 | 43.3 |