Table 7 Quantitative analysis of main compounds in cattle dung bio-oil by GC/MS.

From: Design expert based optimization of the pyrolysis process for the production of cattle dung bio-oil and properties characterization

S. N.

Retention time (min)

Compound

Chemical formula

Chemical group

Concentration (%)

1

4.29

2-Picoline

C6H7N

Pyridine derivatives

2.62

2

4.72

2-Cyclopentenone-1

C5H6O

Ketone

6.76

3

4.89

2-Methylcyclopentan-1-one

C6H10O

Ketone

0.56

4

5.04

Di(2-ethylbutyl) ether

C12H26O

Ether

0.21

5

5.14

Hexanoic acid

C6H12O2

Acid

0.50

6

5.50

Allyl-butanoate

C7H12O2

Ester

0.21

7

5.74

2-Furylmethanol

C5H6O2

Alcohol

7.88

8

5.95

1,2-Ethanediol diacetate

C6H10O4

Ester

5.95

9

6.17

2,4-Hexadienal

C6H8O

Aldehyde

0.19

10

6.42

2,6-Lutidine

C7H9N

Pyridine derivatives

0.39

11

7.22

2-Methyl-2-cyclopenten-1-one

C6H8O

Ketone

5.18

12

7.46

2-Acetyl-furan

C6H6O2

Furan

1.28

13

7.60

3-Oxo-1-butenyl 2-methylpropanoate

C8H12O3

Ester

0.77

14

7.95

Adipic ketone

C5H8O

Ketone

4.83

15

8.34

2-Cyclohexen-1-one

C6H8O

Ketone

0.33

16

8.45

2,5-Dimethylpyridine

C7H9N

Pyridine

0.34

17

8.95

2,3-Dimethylpyridine

C7H9N

Pyridine

0.82

18

9.48

4-Hydroxypentanoic acid lacton

C5H8O2

Furanone

0.38

19

9.93

3-Methyl-2-cyclopentenon

C6H8O

Ketone

4.25

20

10.07

2-Oxobutyl acetate

C6H10O3

Ester

0.62

21

11.15

4,4-Dimethyl-2-cyclopenten-1-one

C7H10O

Ketone

0.61

22

11.30

2,3-Dimethylcyclopent-2-en-1-one

C7H10O

Ketone

0.45

23

11.65

Phenyl alcohol

C6H6O

Alcohol

6.55

24

11.84

n-Butyric anhydride

C8H14O

Anhydride

13.12

25

13.47

Corylon

C6H8O2

Ketone

9.98

26

14.02

(6E)-3,5-Dimethyl-1,6-octadiene

C10H18

Alkene

0.27

27

14.35

1-Oxacyclohexan-2-one

C5H8O2

Ketone

0.31

28

15.14

ortho-Cresol

C7H8O

Phenol

1.54

29

15.92

4-Methoxyphenol

C7H8O2

Phenol

5.24

30

17.12

2-Amino-5,6-dihydro-4,4,6-trimethyl-4H-1,3-oxazine

C7H14N2O

Oxazine

0.97

31

17.69

2-Hydroxy-3-ethyl-2-cyclopenten-1-one

C7H10O2

Ketone

1.54

32

19.28

11-Fluoroundecyl trimethylsilyl ether

C14H31FOSi

Ether

0.38

33

20.74

para-Ethylphenol

C8H10O

Phenol

1.44

34

23.69

2,3-Dihydro-benzofuran

C8H8O

Benzofuran

2.71

35

24.89

4-Ethyl guaiacol

C9H12O2

Phenol

0.48

36

25.38

Hex-1-en-3-yl acetate

C8H14O2

Ester

0.34

37

26.71

4-Vinyl-guaiacol

C9H10O2

Phenol

0.42

38

28.35

2,6-Dimethoxyphenol

C8H10O3

Phenol

2.06

39

29.76

5,5-Diethyl-4-methylene-1,2-dioxolan-3-one

C8H12O3

Ketone

0.29

40

43.45

Desaspidinol

C11H14O4

Phenol

0.20

41

45.59

5,10-Diethoxy-2,3,7,8-tetrahydro-1H,6H-dipyrrolo[1,2-a:1ʹ,2ʹ-d]pyrazine

C14H22N2O2

Pyrazine

0.21

42

49.42

Phthalic acid, bis(2-ethylhexyl) ester (6CI,8CI)

C24H38O4

Ester

0.69