Table 5 Comparison of SBA-15@Schiff‐base@Fe(III) catalyst with other catalysts in the literature to synthesize 4a (Entries 1–10) and 6a (Entries 11–20).

From: Synthesis of 3,4-dihydropyrimidines and octahydroquinazolinones by SBA-15 supported schiff-base iron (III) complex as durable and reusable catalyst under ultrasound irradiation

Entry

Catalyst

Condition

Time

Yield (%)ref

1

PANIFeCl3

CH3CN, reflux

24 h

8341

2

Cellulose sulfuric acid

Water, 100 °C

3.5–6.5 h

8546

3

Fe(III)/Al-MCM-41

CH3CN, reflux

4 h

8547

4

Cu-Schiff base-MCM-41

MeOH, RT

15 min

928

5

MNP–IL–HSO4

solvent-free, 100 °C

30 min

9548

6

Bentonite/PS-SO3H

solvent-free, 120 °C

30 min

8913

7

Nano-Fe3O4-bpy-Ni(II)

MW, Solvent- free,130 °C

1 h

9012

8

SBA‑15@APTES

EtOH, U.S (r.t.)

1 h

Trace (This work)

9

Schiff‐base

EtOH, U.S (r.t.)

1 h

Trace (This work)

10

SBA-15@Schiff‐base@Fe(III)

EtOH, U.S (r.t.)

12 min

>93 (This work)

11

MNPs-BSAT

100 °C, solvent-free

1 h

9411

12

Cu/SiO2

EtOH, reflux

35 min

9649

13

VNPRP

MeOH:H2O (1:1)

1.5 h

9050

14

Nafion-H

EtOH, reflux

10 h

7051

15

SiO2-NaHSO4

H2O, 60–80 °C

1.5 h

9552

16

TMSCl

CH3CN/DMF, reflux

1.5 h

9553

17

VCl3

CH3CN, reflux

2 h

8054

18

SBA‑15@APTES

EtOH, U.S (r.t.)

1 h

Trace (This work)

19

Schiff‐base

EtOH, U.S (r.t.)

1 h

Trace (This work)

20

SBA-15@Schiff‐base@Fe(III)

EtOH, U.S (r.t.)

15 min

>95 (This work)