Table 1 BTO and SRO layer thicknesses, \(t_\textrm{BTO}\) and \(t_\textrm{SRO}\), resulting from grazing X-ray reflectivity (see “Methods”, “Grazing X-ray reflectivity” and Supplementary Fig. 1). All substrates are 0.5 mm thick. The root mean square surface roughness \(S_\textrm{RMS}\) of BTO thin films was determined from AFM images of \(3.9\times 3.9\,\upmu \hbox {m}^2\) area. Compressive in-plane strain in BTO (\(\varepsilon ^{a}_\textrm{BTO}\)) thin films, measured by X-ray reciprocal space maps (Fig. 2a–c). Orientation of the average BTO polarization \(\textrm{P}\) measured by PFM (Fig. 2d–f).

From: Surface polarization profile of ferroelectric thin films probed by X-ray standing waves and photoelectron spectroscopy

Acronym

Sample

\(t_\textrm{BTO}\) (nm)

\(S_\textrm{RMS}\) (nm)

\(t_\textrm{SRO}\) (nm)

\(\varepsilon ^{a}_\textrm{BTO}\) (%)

\(\textrm{P}\)

BTO/SRO/DSO

\(\hbox {BaTiO}_3\)/\(\hbox {SrRuO}_3\)/\(\hbox {DyScO}_3\)

20

0.95

26

-1.23

\(\downarrow\)

BTO/SRO/GSO

\(\hbox {BaTiO}_3\)/\(\hbox {SrRuO}_3\)/\(\hbox {GdScO}_3\)

37

0.77

24

-0.63

\(\uparrow\)

BTO/SRO/SSO

\(\hbox {BaTiO}_3\)/\(\hbox {SrRuO}_3\)/\(\hbox {SmScO}_3\)

35.5

0.81

20

-0.38

\(\uparrow\)