Table 1 BTO and SRO layer thicknesses, \(t_\textrm{BTO}\) and \(t_\textrm{SRO}\), resulting from grazing X-ray reflectivity (see “Methods”, “Grazing X-ray reflectivity” and Supplementary Fig. 1). All substrates are 0.5 mm thick. The root mean square surface roughness \(S_\textrm{RMS}\) of BTO thin films was determined from AFM images of \(3.9\times 3.9\,\upmu \hbox {m}^2\) area. Compressive in-plane strain in BTO (\(\varepsilon ^{a}_\textrm{BTO}\)) thin films, measured by X-ray reciprocal space maps (Fig. 2a–c). Orientation of the average BTO polarization \(\textrm{P}\) measured by PFM (Fig. 2d–f).
Acronym | Sample | \(t_\textrm{BTO}\) (nm) | \(S_\textrm{RMS}\) (nm) | \(t_\textrm{SRO}\) (nm) | \(\varepsilon ^{a}_\textrm{BTO}\) (%) | \(\textrm{P}\) |
|---|---|---|---|---|---|---|
BTO/SRO/DSO | \(\hbox {BaTiO}_3\)/\(\hbox {SrRuO}_3\)/\(\hbox {DyScO}_3\) | 20 | 0.95 | 26 | -1.23 | \(\downarrow\) |
BTO/SRO/GSO | \(\hbox {BaTiO}_3\)/\(\hbox {SrRuO}_3\)/\(\hbox {GdScO}_3\) | 37 | 0.77 | 24 | -0.63 | \(\uparrow\) |
BTO/SRO/SSO | \(\hbox {BaTiO}_3\)/\(\hbox {SrRuO}_3\)/\(\hbox {SmScO}_3\) | 35.5 | 0.81 | 20 | -0.38 | \(\uparrow\) |