Table 3 Kinetic parameters for the adsorption of Pb(II) onto HS and HSN Sahara plants derived adsorbents samples.
HS | HSN | |
|---|---|---|
Kinetic parameter | ||
qeexp (mg/g) | 37.7 | 48.9 |
Pseudo-1st -order kinetic equation | ||
qe1(mg/g) | 4.27 | 9.103 |
k1 (1/min) | 5.48 × 10− 3 | 0.01 |
R2 | 0.125 | 0.233 |
χ2 | 10315.76 | 4710.2 |
SSE | 44048.29 | 42862.84 |
MSE | 4894.25 | 6123.3 |
PseudoSecond-2nd -order kinetic equation | ||
qe2 (mg/g) | 37.02 | 48.23 |
k2 [g/(mg min)] | 0.0155 | 9.90 × 10− 3 |
R2 | 0.998 | 0.998 |
χ2 | 492.066 | 307.06 |
SSE | 18216.3 | 14,809 |
MSE | 2024.032 | 2115.623 |
Intraparticle diffusion equation | ||
kint [mg/(g min1/2)] | 0.594 | 1.508 |
c (mg/g) | 28.69 | 29.75 |
R2 | 0.321 | 0.394 |
Boyd equation | ||
Intercept | 1.702 | 1.251 |
R2 | 0.125 | 0.239 |