Table 7 EIS parameters for CS in 0.5 M H2SO4 without and with 9 × 10− 5 M of KB1 and KB2 at various immersion times.
Compound | Time, h | Rs, Ω cm² | Rct, Ω cm²± SD | Goodness of fit(x10− 3) | θ | %IE |
|---|---|---|---|---|---|---|
Blank | 0.5 | 2.124 | 69.44 ± 1.69 | 5.528 | – | – |
1 | 2.105 | 102.3 ± 1.44 | 5.424 | – | – | |
2 | 2.090 | 149.8 ± 2.08 | 5.673 | – | – | |
3 | 2.215 | 131.5 ± 2.16 | 4.560 | – | – | |
4 | 2.109 | 229.0 ± 1.76 | 5.487 | – | – | |
5 | 2.120 | 262.0 ± 1.69 | 5.381 | – | – | |
6 | 2.125 | 286.0 ± 1.80 | 5.183 | – | – | |
52 | 2.137 | 699.4 ± 1.31 | 4.691 | – | – | |
93 | 1.985 | 848.0 ± 1.67 | 6.993 | – | – | |
KB1 | 0.5 | 2.750 | 382.3 ± 2.49 | 3.217 | 0.818 | 81.8 |
1 | 2.741 | 652.7 ± 2.16 | 3.597 | 0.843 | 84.3 | |
2 | 2.717 | 787.8 ± 1.67 | 3.310 | 0.810 | 81.0 | |
3 | 2.684 | 1075.0 ± 1.59 | 3.634 | 0.878 | 87.8 | |
4 | 2.653 | 1393.0 ± 1.63 | 3.511 | 0.836 | 83.6 | |
5 | 2.630 | 1832.0 ± 2.74 | 3.813 | 0.857 | 85.7 | |
6 | 2.620 | 2150.0 ± 1.51 | 3.821 | 0.867 | 86.7 | |
52 | 2.641 | 1788.0 ± 1.68 | 3.043 | 0.609 | 60.9 | |
93 | 2.517 | 2453.0 ± 2.49 | 4.539 | 0.654 | 65.4 | |
KB2 | 0.5 | 2.970 | 977.9 ± 1.59 | 3.997 | 0.929 | 92.9 |
1 | 2.923 | 1245.0 ± 1.51 | 4.592 | 0.918 | 91.8 | |
2 | 2.897 | 1540.0 ± 2.94 | 5.014 | 0.903 | 90.3 | |
3 | 2.936 | 1890.0 ± 1.63 | 4.984 | 0.930 | 93.0 | |
4 | 2.936 | 2200.0 ± 1.45 | 5.152 | 0.896 | 89.6 | |
5 | 2.960 | 2420.0 ± 2.45 | 5.170 | 0.892 | 89.2 | |
6 | 2.945 | 2770.0 ± 2.49 | 5.269 | 0.897 | 89.7 | |
52 | 2.558 | 2700.0 ± 1.59 | 4.284 | 0.741 | 74.1 | |
93 | 2.568 | 2685.0 ± 1.40 | 4.463 | 0.684 | 68.4 |