Table 2 Percentage peak area (% ± SD) of volatile compounds from unheated DStA and from heating DStA at 60 °C and 180 °C (8 h).

From: Volatile compounds formed during heating of asymmetric distigmasterol-modified acylglycerols as indicators of thermo-oxidative degradation

Volatiles

RI

DStC-P

DStC-O

DStS-P

DStS-O

Heating temperatures

 

0 °C

60 °C

180 °C

0 °C

60 °C

180 °C

0 °C

60 °C

180 °C

0 °C

60 °C

180 °C

Hydrocarbons

Heptane*

700

           

3 ± 0.2

Octane

800

     

4 ± 0.3a

     

7 ± 0.5b

Nonane

900

 

3 ± 0.2b

2 ± 0.4a

    

2 ± 0.5a

    

1-Decene

986

     

2 ± 0.4b

 

1 ± 0.3a

  

1 ± 0.1a

4 ± 0.7c

Decane

1000

53 ± 2.1e

67 ± 4.5g

5 ± 0.3a

100 ± 0.3

32 ± 2.4c

 

50 ± 3.7e

58 ± 3.6f

4 ± 0.2a

42 ± 2.1d

30 ± 1.8c

10 ± 0.7b

Undecane

1100

9 ± 0.5c

11 ± 0.4d

3 ± 0.1a

   

8 ± 0.5c

11 ± 0.8d

3 ± 0.1a

16 ± 0.9e

11 ± 0.7d

4 ± 0.3b

3-Dodecene

1185

    

8 ± 0.6

       

1-Dodecene

1191

       

3 ± 0.2b

 

1 ± 0.1a

9 ± 0.6c

 

Dodecane

1200

4 ± 0.2c

5 ± 0.2d

2 ± 0.1a

 

6 ± 0.4e

 

6 ± 0.3e

6 ± 0.4f

2 ± 0.1a

7 ± 0.5f

 

3 ± 0.1b

Tridecane

1300

4 ± 0.3b

4 ± 0.1b

1 ± 0.1a

 

12 ± 0.9d

0 ± 0.1a

7 ± 0.5c

7 ± 0.4c

1 ± 0.1a

18 ± 1.1f

15 ± 0.9e

7 ± 0.5c

1-Tetradecene

1391

       

1 ± 0.1a

 

3 ± 0.1b

3 ± 0.2b

1 ± 0.1a

3-Methyleicosane

2072

    

9 ± 0.6

       

Alcohols

3-Methyl-2-pentanol

762

          

16 ± 0.9

 

2-Methyl-3-pentanol#

789

  

4 ± 0.3c

  

2 ± 0.1b

  

4 ± 0.3c

  

0 ± 0.1a

Aldehydes

2-Pentenal#

754

  

11 ± 0.7c

  

8 ± 0.6a

  

11 ± 0.9c

  

10 ± 0.8b

4-Methyl-3-pentenal#

791

  

5 ± 0.3b

  

4 ± 0.3a

  

5 ± 0.3b

   

2-Ethyl-3-methyl-butanal#

847

  

6 ± 0.5b

 

8 ± 0.6c

10 ± 0.6d

  

6 ± 0.5b

  

6 ± 0.2a

2-Methyl-2-hexenal

891

  

2 ± 0.1b

  

1 ± 0.1a

  

1 ± 0.1a

   

Heptanal

901

  

3 ± 0.1a

  

7 ± 0.4c

  

3 ± 0.1a

  

4 ± 0.2b

3,3-Dimethylhexanal

915

  

4 ± 0.2a

  

4 ± 0.2a

      

Octanal

1004

  

1 ± 0.1a

  

9 ± 0.6d

  

2 ± 0.2a

  

6 ± 0.4b

2-Ethylhexenal#

1011

  

5 ± 0.3c

  

2 ± 0.1a

  

7 ± 0.5d

  

4 ± 0.3b

Nonanal

1106

     

9 ± 0.6c

  

1 ± 0.1a

  

7 ± 0.3b

2-Decenal

1250

     

1 ± 0.1a

     

2 ± 0.1b

Ketones

Aceton

511

29 ± 1.8c

     

25 ± 2.0b

 

2 ± 0.1a

   

2-Methyl-3-pentanone#

765

  

11 ± 0.7c

 

13 ± 0.9d

9 ± 0.5b

  

11 ± 0.7c

  

6 ± 0.4a

3-Hydroxy-3-methyl-2-butanone

779

    

13 ± 0.8b

     

0.6 ± 0.1a

 

2-Octanone

988

  

1 ± 0.2a

  

1 ± 0.1a

  

2 ± 0.4b

   

2-Nonanone

1091

     

1 ± 0.1a

  

1 ± 0.1a

   

5-Ethyl-6-methyl-3-hepten-2-one#

1143

  

12 ± 0.9b

  

11 ± 0.6b

  

16 ± 0.8c

  

9 ± 0.6a

Acids

Oleic acid

2115

         

10 ± 0.7

  

Others

  

2 ± 0.1a

8 ± 0.5d

19 ± 1.1g

  

11 ± 0.9f

3 ± 0.1b

9 ± 0.5e

19 ± 1.2g

3 ± 0.8b

9 ± 0.6e

6 ± 0.4c

  1. *: Volatile compounds which possess an odor are shown in bold (based on https://pubchem.ncbi.nlm.nih.gov); #: compounds detected in samples heated at 180 °C; a, b,c… - values marked with the same letter in a rows do not differ statistically at the significance level α = 0.05.
  2. DStA: distigmasterol-modified acylglycerols; DStC-P:1,2-distigmasterylcarbonoyl-3-palmitoyl-sn-glycerol; DStC-O: distigmasterylcarbonoyl-1-oleoyl-sn-glycerol; DStS-P: 1,2-distigmasterylsuccinoyl-3-palmitoyl-sn-glycerol; DStS-O: 2,3-distigmasterylsuccinoyl-1-oleoyl-sn-glycerol.