Table 4 Isotherm constants and correlation coefficients obtained for the removal of Cd2+ ions by CuS nanorods.
Isotherm | Parameters | Value |
|---|---|---|
Langmuir \(\:{q}_{e}=\frac{{Q}_{m}{K}_{L}{C}_{e}}{1+\:{K}_{L}{C}_{e}}\) | Qm (mg g− 1) | 275.4 |
KL (L− 1 mg) | 0.029 | |
R2 | 0.991 | |
Freundlich \(\:{q}_{e}=\:{K}_{F}{C}_{e}^{\raisebox{1ex}{$1$}\!\left/\:\!\raisebox{-1ex}{$n$}\right.}\) | KF (mg g− 1. L mg− 1) | 61.25 |
n | 2.89 | |
R2 | 0.963 | |
D-R \(\:{q}_{e}=\:{q}_{s}\text{e}\text{x}\text{p}(-{K}_{DR}{\left[RT\text{ln}(1+\:\frac{1}{{C}_{e}}\right]}^{2})\) | Qs (mg g− 1) | 263.18 |
KDR (mol2 kJ2) | 0.0021 | |
E (kJ mol− 1) | 15.41 | |
R2 | 0.978 | |
Temkin \(\:{q}_{e}=\frac{RT}{{b}_{T}}\text{l}\text{n}\left({A}_{T}{C}_{e}\right)\) | AT (L mg− 1) | 0.186 |
bT (J mol− 1) | 125.6 | |
R2 | 0.945 |