Table 2 Heavy metals (mg/kg) in cosmetic products reported from Trarkhel, Azad Jammu and Kashmir, Pakistan and compared with the literature.
Nature | Code | Products name | Pb | Cd | Cu | Co | Ag | Ni | Zn | As | Mn | Hg | Techniques | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Lipsticks products | ||||||||||||||
Branded lipsticks | BL1 | Swiss miss/B | 62.2 ± 0.1 | 2.8 ± 0.00 | 316 ± 0.29 | 53.8 ± 0.02 | 3.86 ±0.00 | 118 ± 0.21 | BDL | BDL | 395 ±0.15 | BDL | GAAS | Present Research |
BL3 | Rivaj UK/ B | 26.7 ± 0.03 | 0.86 ± 0.01 | 11.3 ± 0.01 | 10.23 ± 0.03 | BDL | 30.0 ± 0.2 | BDL | BDL | 141 ±0.08 | BDL | |||
BL5 | Miss Rose/ B | 18.9 ± 0.08 | 1.08 ± 0.03 | 0.83 ± 0.00 | 9.03 ± 0.06 | 0.32 ±0.00 | 1.35 ± 0.1 | BDL | BDL | 23.7 ±0.03 | BDL | |||
BL8 | Matte lipstick/B | 0.84 ± 0.00 | 1.13 ± 0.00 | 0.66 ± 0.01 | 7.16 ± 0.07 | 0.16 ±0.00 | 0.68 ± 0.02 | BDL | BDL | 0.75 ±0.00 | BDL | |||
BL9 | Loreal/ B | 5.12 ± 0.03 | 1.1 ± 0.01 | 0.37 ± 0.01 | 14.3 ±0.09 | 0.08 ±0.00 | 0.25 ±0.06 | BDL | BDL | 0.262 ±0.00 | BDL | |||
Mean ( n = 5) | 22.774 | 1.39 | 58.26 | 18.92 | 0.886 | 30.2 | BDL | BDL | BDL | BDL | ||||
Local lipsticks | LL2 | Huxia Beauty/L | 14.6 ± 0.04 | 1.28 ± 0.01 | 258 ± 0.15 | 8.7 ± 0.01 | 1.65±0.01 | 731 ± 3.18 | BDL | BDL | 3.81 ±0.00 | BDL | ||
LL4 | Colour Ingtitute/L | 25.0 ± 0.06 | 1.02 ± 0.00 | 15.1 ± 0.00 | 12.4 ± 0.07 | 0.737±0.00 | 4.13 ± 0.02 | BDL | BDL | 12.6 ±0.01 | BDL | |||
LL6 | Huxia/ L | 49.6 ± 0.1 | 0.98 ± 0.02 | 11.3 ± 0.01 | 9.23 ± 0.01 | 0.1±0.00 | 2.13 ± 0.10 | BDL | BDL | 30.9 ±0.01 | BDL | |||
LL7 | Matte/ L | 20.7 ± 0.1 | 1.1 ± 0.01 | 1.03 ± 0.01 | 6.32 ± 0.02 | 0.162±0.00 | 2.18 ± 0.05 | BDL | BDL | 0.9 ±0.013 | BDL | |||
LL10 | Lipstick/ L | 9.43 ± 0.01 | 2.18 ± 0.01 | 5.16 ± 0.01 | 7.16 ±0.01 | 0.25±0.00 | 3.27 ± 0.05 | BDL | BDL | 189 ±0.03 | BDL | |||
Mean (n = 5) | - | 23.9 | 1.31 | 66.00 | 8.76 | 0.579 | 148 | BDL | BDL | BDL | BDL | |||
Overall mean (n= 10) | 23.3 | 1.35 | 62.1 | 13.8 | 0.733 | 89.3 | BDL | BDL | BDL | BDL | ||||
Min-Max | 0.85-62.22 | 0.75-2.8 | 0.375-316.87 | 7.16-53.8 | 1.09-3.86 | 0.25-731 | BDL | BDL | BDL | BDL | ||||
Literature of lipstick products | ||||||||||||||
Mni-Max | - | 0.0006-429.1 | 0.001-68.2 | <0.02 -135 | 0.0001-19.9 | <0.01-5 | <0.012-174 | <0.03-123 | 0.012-14.1 | 0.28-151 | 0.075-80 | GAAS | ||
Beauty Cream Products | ||||||||||||||
Branded beauty cream | BBC11 | Sandal beauty cream/B | 11.6 ± 0.02 | 1.31 ± 0.01 | 30.9 ± 0.01 | 243.5 | 0.53 ± 0.00 | 103 ± 0.05 | 400 ±0.01 | 2.68 ± 0.03 | 0.15±0.01 | 3047±0.05 | GAAS | Present Research |
BBC14 | Sunblock/B | 11.0 ± 0.05 | 1.23 ± 0.00 | 0.287 ± 0.01 | 10.9 ± 0.06 | 0.18 ± 0.00 | 0.32 ± 0.01 | 14.3 ±0.01 | BDL | 0.15±0.00 | 18.2 ±0.02 | |||
BBC15 | Lady dania Sun block /B | 9.51 ± 0.1 | 1.28 ± 0.01 | 0.275 ± 0.01 | BDL | 0.45 ± 0.00 | 0.67 ± 0.06 | 4.12 ±0.01 | BDL | 0.125±0.00 | 2.5 ±0.01 | |||
BBC17 | Rivaj sunblock/B | BDL | 1.2 ± 0.01 | 0.5 ± 0.01 | BDL | 0.43 ± 0.00 | 0.66 ± 0.02 | BDL | BDL | 0.025±0.00 | BDL | |||
BBC19 | Johnson cream/B | 9.2 ± 0.1 | 1.55 ± 0.00 | 0.312 ± 0.00 | 6.37 ± 0.06 | 0.28 ± 0.00 | 0.31 ± 0.03 | BDL | BDL | 0.075±0.00 | BDL | |||
BBC20 | Himalaya cream/B | BDL | 1.23 ± 0.02 | 0.237 ± 0.00 | 4.62 ± 0.03 | 0.25 ± 0.00 | 0.88 ± 0.1 | BDL | 0.43 ±0.01 | 0.105±0.00 | BDL | |||
Mean (n = 5) | 6.902 | 1.30 | 5.41 | 44.2 | 0.358 | 17.64 | 69.8 | 0.520 | 0.105 | 511.37 | ||||
Local beauty cream | LBC12 | Face fresh beauty cream/L | 7.1 ± 0.1 | 2.67 ± 0.02 | 0.512 ± 0.01 | 15.1 ± 0.02 | 0.325 ± 0.00 | 1.91 ± 0.01 | 996 ±0.05 | BDL | 0.175 ±0.00 | 344 ±0.01 | ||
LBC13 | Marvi Beauty cream/L | 4.52 ± 0.1 | 1.02 ± 0.01 | 0.787 ± 0.01 | 9.17 ± 0.02 | 0.57 ± 0.00 | 2.75 ± 0.03 | 49.3 ±0.02 | BDL | 0.075 ±0.00 | 167 ±0.03 | |||
LBC16 | Snow cream/L | 9.0 ± 0.08 | 0.95 ± 0.01 | 0.287 ± 0.00 | 0.05 ± 0.02 | 0.187 ± 0.00 | 0.037 ± 0.06 | 5.62 ±0.21 | BDL | 0.062 ±0.00 | BDL | |||
LBC18 | Chiltan pure acene cream/L | BDL | 1.05 ± 0.02 | 1.12 ± 0.01 | BDL | 0.387 ± 0.01 | 0.262 ± 0.1 | 1.62 ±0.03 | BDL | 0.1 ±0.00 | 5.25 ±0.01 | |||
Mean (n = 5) | - | 5.15 | 1.42 | 0.678 | 6.10 | 0.368 | 1.240 | 263 | BDL | BDL | 129 | |||
Overall mean (n = 10) | 6.21 | 1.35 | 3.52 | 28.9 | 0.362 | 11.0 | 166 | 1.56 | 0.105 | 358 | ||||
Min-max | BDL-11.6 | 0.95-0-2.67 | 0.019-2.47 | BDL-1.21 | 0.125-0.537 | 0.021-8.241 | BDL-400 | 0.43-2.68 | 0.025-0.175 | BDL - 3047 | ||||
Literature of beauty cream products | ||||||||||||||
Min-max | 0.005-1266 | 0.005-466 | 0.016-65.3 | <0.02-40.25 | <0.01-100 | 0.016-41.5 | 0.006-12.14 | 0.005-466.7 | 0.005-466.7 | 0.0045-14,507 | ||||
Nail polishes | ||||||||||||||
Branded Nail Polish | BNP26 | Xuncai/B | BDL | 1.42 ± 0.01 | 0.56 ± 0.01 | 5.91 ±0.04 | 0.33 ±0.00 | BDL | BDL | BDL | 0.187± 0.00 | BDL | GFAAS | Present research |
BNP27 | Colorist/B | BDL | 1.51 ± 0.01 | 0.45 ± 0.01 | 4.46 ±0.08 | 0.25 ±0.00 | BDL | BDL | BDL | 11± 0.03 | BDL | |||
BNP28 | Sweet touch London/B | BDL | 1.58 ± 0.00 | 0.25 ± 0.01 | 4.82 ±0.02 | 0.3 ±0.010 | BDL | BDL | BDL | 0.225± 0.00 | BDL | |||
BNP29 | Face cover/B | BDL | 1.66 ± 0.01 | 0.46 ± 0.00 | 7.98 ±0.01 | 0.27 ±0.01 | BDL | BDL | BDL | 0.25± 0.01 | BDL | |||
BNP30 | Xuancai/B | 2.97 ± 0.08 | 1.51 ± 0.04 | 0.25 ± 0.00 | 0.4 ±0.02 | 0.35 ±0.00 | BDL | BDL | BDL | BDL± 0.00 | BDL | |||
Mean (n =5) | 0.59 | 1.54 | 0.395 | 4.71 | 0.302 | BDL | BDL | BDL | 2.3324 | BDL | ||||
Local Nail Polish | LNP21 | HD Romantic collars/L | BDL | 1.28 ± 0.01 | 0.62 ± 0.01 | 11.4 ±0.09 | 0.37 ±0.00 | 0.712 ± 0.1 | BDL | BDL | 0.62 ± 0.01 | BDL | ||
LNP22 | Mode love/L | BDL | 1.56 ± 0.01 | 46.3 ± 0.73 | 5.61 ±0.04 | 0.23 ±0.00 | 0.212 ± 0.04 | BDL | BDL | 0.05± 0.00 | BDL | |||
LNP23 | Christin/L | BDL | 1.28 ± 0.02 | 0.27 ± 0.00 | 1.52 ±0.02 | 0.25 ±0.00 | BDL | BDL | BDL | 0.025± 0.00 | BDL | |||
LNP24 | AIR Woman/L | 1.4 ± 0.01 | 1.55 ± 0.02 | 0.37 ± 0.01 | 6.92 ±0.03 | 0.25 ±0.00 | BDL | BDL | BDL | 0.337± 0.002 | BDL | |||
LNP25 | Mendon nail polish/L | 2.97 ± 0.01 | 1.52 ± 0.00 | 0.41 ± 0.00 | 12.7 ±0.02 | 0.3 ±0.011 | BDL | BDL | BDL | 1.02± 0.01 | BDL | |||
Mean (n = 5) | - | 0.87 | 1.44 | 9.61 | 7.65 | 0.282 | 0.185 | BDL | BDL | 0.410 | BDL | |||
Overall Mean (n =10) | 0.43 | 1.49 | 5.00 | 6.18 | 0.292 | 0.092 | BDL | BDL | BDL | |||||
Min-Max | BDL -2.97 | 1.28 -1.66 | 0.25-46.3 | 0.4-1.12.7 | 0.237-0.375 | BDL -0.712 | BDL | BDL | BDL-11 | BDL | ||||
Literature of Nail Polish Product | ||||||||||||||
Min-Max | <0.1-42 | 0.01-8.12 | 0.5-30 | <0.01-1 | 0.1-5 | 1.88-4.22 | - | - | 0.76-6.32 | - | ||||
