Table 1 Mean parameter changes during each of the four experiments. Differences (\(\Delta\)) are based on pre-dosing background measurements taken immediately prior to dosing during each experimental day. The values of TCO\(_2\) and Alk are from discrete samples, and the signal strength is computed on the basis of the NaOH addition and Alk samples at corresponding sample locations. NF1 = near field 1 position, NF2 = near field 2 position (see Fig. 5c) for sample locations. Parameter mean signals at each location as reported with standard deviation (stdev) in brackets, (-) indicates only one sample was taken and there is no stdev.

From: Alkalinity enhancement with sodium hydroxide in coastal ocean waters

Experiment

Position

\(\Delta\)pCO\(_2\)

\(\Delta\)TCO\(_2\)

\(\Delta\)Alk

\(\Delta\)pH

Signal strength

Mean pCO\(_2\)

Mean TCO\(_2\)

Mean Alk

Mean pH

\(\mu\)atm

\(\mu\)mol kg\(^{-1}\)

\(\mu\)mol kg\(^{-1}\)

\(\%\)

\(\mu\)atm

\(\mu\)mol kg\(^{-1}\)

\(\mu\)mol kg\(^{-1}\)

1

Release

38

0

36

0.05

2.2

408

(25)

2044

(19)

2265

(19)

8.03

(0.03)

NF1

28

-

-

0.03

-

407

(5)

-

-

8.01

(0.01)

NF2

10

0

5

0.01

0.5

436

(3)

2058

(-)

2247

(-)

7.99

(0.00)

Downstream

43

-2

29

0.05

2.8

403

(16)

2055

(-)

2271

(-)

8.03

(0.02)

2

Release

338

2

544

0.71

49.4

107

(57)

2059

(n=1)

2787

(-)

8.69

(0.03)

NF1

15

-2

6

0.01

0.51

431

(8)

2055

(-)

2248

(-)

7.99

(0.00)

NF2

10

4

9

0.01

0.8

435

(8)

2061

(-)

2251

(-)

7.99

(0.01)

Downstream

54

6

49

0.06

4.5

391

(14)

2063

(-)

2291

(-)

8.05

(0.01)

3

Release

209

6

139

0.27

12.5

286

(32)

2077

(-)

2378

(-)

8.22

(0.02)

NF1

-4

4

1

-0.01

0.1

498

(18)

2075

(-)

2240

(-)

7.65

(0.00)

NF2

7

-3

0

0.01

0.0

488

(13)

2068

(-)

2239

(-)

7.69

(0.01)

Downstream

8

0

7

0.01

0.6

487

(14)

2071

(-)

2246

(-)

7.97

(0.01)

4

Release

158

3

69

0.18

6.2

337

(26)

2074

(-)

2308

(-)

8.13

(0.04)

NF1

-20

5

0

-0.02

0.0

515

(9)

2075

(-)

2239

(-)

7.94

(0.00)

NF2

7

-9

0

0.01

0.0

486

(1)

2062

(-)

2239

(-)

7.96

(0.00)

Downstream

62

-4

34

0.05

3.1

433

(17)

2067

(-)

2273

(-)

8.00

(0.02)

Pre-experiment

      

445

(20)

1898

(56)

2062

(61)

7.96

(0.01)

Post-experiment

      

458

(17)

1932

(23)

2109

(26)

7.97

(0.02)