Table 1 1H and 13C NMR data of Jatrophenins 1 and 2 (500/125 MHz, DMSO-d6)
No | 1 | Marzouk et al., 201235 | 2 | Marzouk et al., 201235 | ||||
|---|---|---|---|---|---|---|---|---|
δH | δC | δH | δC | δH | δC | δH | δC | |
B 1,4-Glucose | ||||||||
1 | 6.21 d (7.5) | 92.65 | 6.22 d (7.1) | 92.13 | 6.20d (7.0) | 92.65 | 6.24 d (7.9) | 91.80 |
2 | 3.88br d (7.5) | 71.99 | 3.89 br d (7.1) | 71.50 | 3.88br d (7.5) | 72.00 | 3.70 br d (6.8) | 71.77 |
3 | 4.59 br s | 77.91 | 4.62 br s | 77.31 | 4.59br s | 77.93 | 4.53 br s | 79.48 |
4 | 4.22br s | 62.60 | 4.23 br s | 62.06 | 4.22br s | 62.60 | 4.14 br s | 63.04 |
5 | 4.36 t-like (8.5) | 76.76 | 4.37 t-like (8.2) | 76.25 | 4.35 t-like (8.5) | 76.77 | 4.35 t-like (8.7) | 76.11 |
6a 6b | 4.23 dd (11.5, 8.0) 3.96dd (10.9, 8.9) | 64.39 | 4.24 dd (11.2, 7.9) 3.98 dd (10.9, 8.9) | 63.86 | 4.22 m 3.96dd(10.5,8.5) | 64.39 | 4.18 m 3.98 br t-like (10.2) | 64.06 |
Galloyl | ||||||||
1′ | 119.13 | 118.64 | 119.13 | 118.99 | ||||
2′,6′ | 7.01 s | 109.49 | 7.03 s | 108.93 | 7.01 s | 109.45 | 7.04 s | 108.32 |
3′,5′ | 146.01 | 145.49 | 146.01 | 145.78 | ||||
4′ | 139.47 | 138.80 | 139.47 | 139.19 | ||||
7′ | 165.31 | 164.72 | 165.30 | 165.22 | ||||
HHDP/Val | ||||||||
1′′,1′′′ | 116.25, 115.95 | 115.71, 115.42 | 116.25, 120.86 | 115.77, 117.89 | ||||
2′′,2′′′ | 124.32, 123.55 | 123.82, 123.01 | 123.55, 124.32 | 122.94, 123.74 | ||||
3′′ | 6.49 | 107.40 | 6.51 s | 106.88 | 6.56 s | 107.40 | 6.55 s | 108.40 |
4′′,4′′′ | 145.29, 145.20 | 144.73, 144.64 | 145.20, 148.78 | 144.50, 146.00 | ||||
5′′,5′′′ | 135.99, 135.84 | 135.44, 135.31 | 136.74, 135.99 | 136.20, 136.10 | ||||
6′′,6′′′ | 144.73, 144.40 | 144.21, 143.89 | 14,529, 145.82 | 144.66, 145.77 | ||||
7′′,7′′′ | 167.58, 167.22 | 166.99, 166.64 | 167.58, 167.96 | 167.20, 167.44 | ||||
3′′′ | 6.56 s | 106.45 | 6.58 s | 106.01 | 6.49 s | 106.45 | 6.49 s | 106.21 |
1′′′′ | 115.95 | 114.70 | ||||||
2′′′′ | 144.74 | 142.47 | ||||||
3′′′′ | 6.92 s | 135.84 | 6.94 s | 135.73 | ||||
4′′′′ | 138.44 | 139.20 | ||||||
5′′′′ | 144.40 | 139.22 | ||||||
6′′′′ | 109.15 | 108.99 | ||||||
7′′′′ | 167.22 | 167.10 | ||||||
