Table 1 Comparative GC-MS analysis of n-hexane extracts and EOs of Thymus vulgaris (TV) and Thymus serpyllum (TS).
SN | Compound | Chemical Class | Rt | M.F. | M.W. | RI Cal. | RI Lit. | Area % | ||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
REF | TSV | TVV | TSH | TVH | ||||||||
1 | 1-Octen-3-ol | Unsaturated aliphatic alcohol | 8.48 | C8H16O | 128.21 | 976 | 976 | – | – | 0.63 | – | – |
2 | α-Phellandrene | Monoterpene hydrocarbon | 9.34 | C10H16 | 136.23 | 1005 | 1005 | – | 0.15 | – | – | – |
3 | p-Cymene | Aromatic monoterpene | 9.80 | C10H14 | 134.22 | 1020 | 1022 | 10.3 | 1.29 | 2.27 | – | – |
4 | Eucalyptol | Monoterpene oxide | 9.99 | C10H18O | 154.25 | 1026 | 1028 | – | – | 1.53 | – | – |
5 | γ-Terpinene | Monoterpene hydrocarbon | 10.86 | C10H16 | 136.23 | 1054 | 1054 | – | 0.81 | 1.06 | – | – |
6 | Bicyclo[3.1.0]hexan-2-ol, 2-methyl-5-(1-methylethyl)-, (1α,2β,5α)- | Monoterpene alcohol | 11.12 | C10H18O | 154.25 | 1062 | 1057 | – | – | 1.89 | – | – |
7 | Terpinolene | Monoterpene hydrocarbon | 12.08 | C10H16 | 136.23 | 1094 | 1094 | – | – | 0.49 | – | – |
8 | Linalool | Monoterpene alcohol | 12.15 | C10H18O | 154.25 | 1096 | 1097 | – | – | 2.5 | – | – |
9 | Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1 S)- | Monoterpene ketone | 13.50 | C10H16O | 152.23 | 1140 | 1139 | – | – | 0.84 | – | – |
10 | Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, (1 S-endo)- | Monoterpene alcohol | 14.19 | C10H18O | 154.25 | 1162 | 1166 | – | - | 2.25 | – | – |
11 | Terpinen-4-ol | Monoterpene alcohol | 14.54 | C10H18O | 154.25 | 1174 | 1174 | – | 0.38 | 0.85 | – | – |
12 | α-Terpineol | Monoterpene alcohol | 14.96 | C10H18O | 154.25 | 1187 | 1189 | – | – | 0.23 | – | – |
13 | Benzene, 2-methoxy-4-methyl-1-(1-methylethyl)- | Aromatic ether (phenylpropanoid) | 16.25 | C11H16O | 164.24 | 1231 | 1231 | – | – | 0.34 | – | – |
14 | Thymoquinone | Monoterpene quinone | 16.70 | C10H12O2 | 164.20 | 1248 | 1248 | – | – | – | 0.39 | 1.04 |
15 | Thymol | Phenolic monoterpenoid | 18.05 | C10H14O | 150.22 | 1293 | 1290 | 9.32 | 74.47 | 78.21 | 10.9 | 44.6 |
16 | Carvacrol | Phenolic monoterpenoid | 18.29 | C10H14O | 150.22 | 1301 | 1300 | 80.37 | - | 3.69 | – | 4.27 |
17 | (1 S,2R,4R,7R)-4-Isopropyl-7-methyl-3,8-dioxatricyclo[5.1.0.02,4]octane | Oxygenated monoterpenoid | 18.41 | C10H16O2 | 168.23 | 1306 | 1306 | – | – | – | – | 0.67 |
18 | 3’,5’-Dimethoxyacetophenone | Aromatic ketone | 21.22 | C10H12O3 | 180.08 | 1407 | 1407 | – | 2.38 | – | – | |
19 | Caryophyllene | Sesquiterpene hydrocarbon | 21.50 | C15H24 | 204.35 | 1418 | 1418 | – | 9.89 | 1.62 | – | – |
20 | trans-α-Bergamotene | Sesquiterpene hydrocarbon | 21.88 | C15H24 | 204.35 | 1432 | 1431 | – | 0.98 | – | – | – |
21 | Humulene | Sesquiterpene hydrocarbon | 22.40 | C15H24 | 204.35 | 1452 | 1452 | – | 0.71 | – | – | – |
22 | α-Selinene | Sesquiterpene hydrocarbon | 23.27 | C15H24 | 204.35 | 1485 | 1485 | – | 3.37 | – | – | – |
23 | β-Selinene | Sesquiterpene hydrocarbon | 23.50 | C15H24 | 204.35 | 1494 | 1494 | – | 0.44 | – | – | – |
24 | Caryophyllene oxide | Oxygenated sesquiterpene | 25.73 | C15H24O | 220.35 | 1584 | 1583 | – | 1.06 | 1.6 | 0.49 | – |
25 | Epicubenol | Sesquiterpene alcohol | 26.49 | C15H26O | 222.37 | 1615 | 1616 | – | 0.39 | – | – | – |
26 | τ-Cadinol | Sesquiterpene alcohol | 27.09 | C15H26O | 222.37 | 1641 | 1640 | – | 0.72 | – | – | – |
27 | (Z)-γ-Atlantone | Sesquiterpene ketone | 28.35 | C15H22O | 218.33 | 1694 | 1698 | – | 0.23 | – | – | - |
28 | (Z)-α-Atlantone | Sesquiterpene ketone | 28.99 | C15H22O | 218.33 | 1721 | 1717 | – | 0.59 | – | – | - |
29 | Bis(2-ethylhexyl) phthalate | Phthalate ester | 44.46 | C24H38O4 | 390.56 | 2546 | 2544 | – | – | – | 0.86 | 2.28 |
30 | Ethyl hexacosyl ether | Long-chain aliphatic ether | 49.54 | C28H58O | 410.76 | 2889 | 2891 | – | – | – | 0.38 | 2.51 |
31 | Hexacosyl propyl ether | Long-chain aliphatic ether | 50.91 | C29H60O | 424.79 | 2989 | 2982 | – | – | – | - | 0.79 |
32 | Ethyl octacosyl ether | Long-chain aliphatic ether | 52.24 | C30H62O | 438.81 | 3089 | 3086 | – | – | – | 1.07 | 7.52 |
33 | 2-Methylhentriacontane | Higher alkane | 53.20 | C32H66 | 450.87 | 3162 | 3160 | – | – | – | – | 0.7 |
34 | Octacosyl propyl ether | Long-chain aliphatic ether | 53.53 | C31H64O | 452.84 | 3188 | 3178 | – | – | – | 0.4 | 2.32 |
35 | Octyl tetracosyl ether | Long-chain aliphatic ether | 54.41 | C32H66O | 466.87 | 3250 | 3252 | – | – | – | 1.38 | 0.77 |
36 | Tritriacontane | Higher alkane | 55.04 | C33H68 | 464.89 | 3295 | 3300 | – | – | – | 22.79 | 26.53 |
37 | Nonyl tetracosyl ether | Long-chain aliphatic ether | 55.96 | C33H68O | 480.89 | 3350 | 3350 | – | – | – | 0.28 | – |
38 | Heptyl hexacosyl ether | Long-chain aliphatic ether | 56.17 | C33H68O | 480.89 | 3363 | 3358 | – | – | – | 0.72 | 1.61 |
39 | Tetratriacontane | Higher alkane | 56.63 | C34H70 | 478.92 | 3390 | 3400 | – | – | – | 3.76 | – |
40 | Tritriacontane, 3-methyl- | Branched alkane | 56.60 | C34H70 | 478.92 | 3388 | 3380 | – | – | – | - | 2.04 |
41 | Urs-12-en-3-ol, acetate, (3β)- | Triterpenoid ester | 57.39 | C32H52O2 | 468.75 | 3507 | 3486 | – | – | – | 0.8 | – |
42 | 3-Methylpentatriacontane | Branched alkane | 57.80 | C36H74 | 506.97 | 3536 | 3536 | – | – | – | 7.4 | – |
43 | Hexatriacontane | Higher alkane | 58.66 | C36H74 | 506.97 | 3597 | 3600 | – | – | – | 44.2 | 2.36 |
44 | Nonyl octacosyl ether | Long-chain aliphatic ether | 60.79 | C37H76O2 | 537.00 | 3742 | 3747 | – | – | – | 1.63 | – |
45 | Butyl tetratriacontyl ether | Long-chain aliphatic ether | 62.41 | C38H78O | 551.03 | 3854 | 3892 | – | – | – | 0.99 | – |