Table 1 Comparative GC-MS analysis of n-hexane extracts and EOs of Thymus vulgaris (TV) and Thymus serpyllum (TS).

From: Comparative chemical and biological study of essential oils and n-hexane extracts of Thymus vulgaris and Thymus serpyllum (Lamiaceae)

SN

Compound

Chemical Class

Rt

M.F.

M.W.

RI Cal.

RI Lit.

Area %

REF

TSV

TVV

TSH

TVH

1

1-Octen-3-ol

Unsaturated aliphatic alcohol

8.48

C8H16O

128.21

976

976

0.63

2

α-Phellandrene

Monoterpene hydrocarbon

9.34

C10H16

136.23

1005

1005

0.15

3

p-Cymene

Aromatic monoterpene

9.80

C10H14

134.22

1020

1022

10.3

1.29

2.27

4

Eucalyptol

Monoterpene oxide

9.99

C10H18O

154.25

1026

1028

1.53

5

γ-Terpinene

Monoterpene hydrocarbon

10.86

C10H16

136.23

1054

1054

0.81

1.06

6

Bicyclo[3.1.0]hexan-2-ol, 2-methyl-5-(1-methylethyl)-, (1α,2β,5α)-

Monoterpene alcohol

11.12

C10H18O

154.25

1062

1057

1.89

7

Terpinolene

Monoterpene hydrocarbon

12.08

C10H16

136.23

1094

1094

0.49

8

Linalool

Monoterpene alcohol

12.15

C10H18O

154.25

1096

1097

2.5

9

Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1 S)-

Monoterpene ketone

13.50

C10H16O

152.23

1140

1139

0.84

10

Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, (1 S-endo)-

Monoterpene alcohol

14.19

C10H18O

154.25

1162

1166

-

2.25

11

Terpinen-4-ol

Monoterpene alcohol

14.54

C10H18O

154.25

1174

1174

0.38

0.85

12

α-Terpineol

Monoterpene alcohol

14.96

C10H18O

154.25

1187

1189

0.23

13

Benzene, 2-methoxy-4-methyl-1-(1-methylethyl)-

Aromatic ether (phenylpropanoid)

16.25

C11H16O

164.24

1231

1231

0.34

14

Thymoquinone

Monoterpene quinone

16.70

C10H12O2

164.20

1248

1248

0.39

1.04

15

Thymol

Phenolic monoterpenoid

18.05

C10H14O

150.22

1293

1290

9.32

74.47

78.21

10.9

44.6

16

Carvacrol

Phenolic monoterpenoid

18.29

C10H14O

150.22

1301

1300

80.37

-

3.69

4.27

17

(1 S,2R,4R,7R)-4-Isopropyl-7-methyl-3,8-dioxatricyclo[5.1.0.02,4]octane

Oxygenated monoterpenoid

18.41

C10H16O2

168.23

1306

1306

0.67

18

3’,5’-Dimethoxyacetophenone

Aromatic ketone

21.22

C10H12O3

180.08

1407

1407

2.38

 

19

Caryophyllene

Sesquiterpene hydrocarbon

21.50

C15H24

204.35

1418

1418

9.89

1.62

20

trans-α-Bergamotene

Sesquiterpene hydrocarbon

21.88

C15H24

204.35

1432

1431

0.98

21

Humulene

Sesquiterpene hydrocarbon

22.40

C15H24

204.35

1452

1452

0.71

22

α-Selinene

Sesquiterpene hydrocarbon

23.27

C15H24

204.35

1485

1485

3.37

23

β-Selinene

Sesquiterpene hydrocarbon

23.50

C15H24

204.35

1494

1494

0.44

24

Caryophyllene oxide

Oxygenated sesquiterpene

25.73

C15H24O

220.35

1584

1583

1.06

1.6

0.49

25

Epicubenol

Sesquiterpene alcohol

26.49

C15H26O

222.37

1615

1616

0.39

26

τ-Cadinol

Sesquiterpene alcohol

27.09

C15H26O

222.37

1641

1640

0.72

27

(Z)-γ-Atlantone

Sesquiterpene ketone

28.35

C15H22O

218.33

1694

1698

0.23

-

28

(Z)-α-Atlantone

Sesquiterpene ketone

28.99

C15H22O

218.33

1721

1717

0.59

-

29

Bis(2-ethylhexyl) phthalate

Phthalate ester

44.46

C24H38O4

390.56

2546

2544

0.86

2.28

30

Ethyl hexacosyl ether

Long-chain aliphatic ether

49.54

C28H58O

410.76

2889

2891

0.38

2.51

31

Hexacosyl propyl ether

Long-chain aliphatic ether

50.91

C29H60O

424.79

2989

2982

-

0.79

32

Ethyl octacosyl ether

Long-chain aliphatic ether

52.24

C30H62O

438.81

3089

3086

1.07

7.52

33

2-Methylhentriacontane

Higher alkane

53.20

C32H66

450.87

3162

3160

0.7

34

Octacosyl propyl ether

Long-chain aliphatic ether

53.53

C31H64O

452.84

3188

3178

0.4

2.32

35

Octyl tetracosyl ether

Long-chain aliphatic ether

54.41

C32H66O

466.87

3250

3252

1.38

0.77

36

Tritriacontane

Higher alkane

55.04

C33H68

464.89

3295

3300

22.79

26.53

37

Nonyl tetracosyl ether

Long-chain aliphatic ether

55.96

C33H68O

480.89

3350

3350

0.28

38

Heptyl hexacosyl ether

Long-chain aliphatic ether

56.17

C33H68O

480.89

3363

3358

0.72

1.61

39

Tetratriacontane

Higher alkane

56.63

C34H70

478.92

3390

3400

3.76

40

Tritriacontane, 3-methyl-

Branched alkane

56.60

C34H70

478.92

3388

3380

-

2.04

41

Urs-12-en-3-ol, acetate, (3β)-

Triterpenoid ester

57.39

C32H52O2

468.75

3507

3486

0.8

42

3-Methylpentatriacontane

Branched alkane

57.80

C36H74

506.97

3536

3536

7.4

43

Hexatriacontane

Higher alkane

58.66

C36H74

506.97

3597

3600

44.2

2.36

44

Nonyl octacosyl ether

Long-chain aliphatic ether

60.79

C37H76O2

537.00

3742

3747

1.63

45

Butyl tetratriacontyl ether

Long-chain aliphatic ether

62.41

C38H78O

551.03

3854

3892

0.99

  1. REF: Reference market product of thyme oil, TSV: Thymus serpyllum essential oil (EO), TVV: Thymus vulgaris EO, TSH: Thymus serpyllum n-hexane extract, TVH: Thymus vulgaris n-hexane extract. Compounds were identified using Kovet’s indexes and mass spectrum fragmentation chromatograms in the NIST library with a range of ± 5.