Table 7 Comparison of LOD and LOQ values for the proposed green HPLC method versus literature-reported methods.
Method | PAR (µg/mL) | PSE (µg/mL) | CHL (µg/mL) | MET (µg/mL) | PRO (µg/mL) |
|---|---|---|---|---|---|
Proposed Green Method | LOD: 0.87 LOQ: 2.66 | LOD: 0.90 LOQ: 2.73 | LOD: 0.05 LOQ: 0.14 | LOD: 0.06 LOQ: 0.17 | LOD: 0.03 LOQ: 0.09 |
Reported method13 | LOD: 0.05 LOQ: N/A | LOD: 0.08 LOQ: N/A | LOD: 0.08 LOQ: N/A | LOD: 0.05 LOQ: N/A | LOD: 0.05 LOQ: N/A |
Reported method14 | LOD: 0.09 LOQ: 0.27 | LOD: 0.08 LOQ: 0.24 | LOD: 0.08 LOQ: 0.24 | LOD: 0.07 LOQ: 0.21 | LOD: 0.07 LOQ: 0.21 |
Reported method20 | LOD: 0.07 LOQ: 0.21 | LOD: 0.02 LOQ: 0.05 | LOD: 0.46 LOQ: 1.38 | LOD: N/A LOQ: N/A | LOD: N/A LOQ: N/A |
Reported method21 | LOD: N/A LOQ: N/A | LOD: N/A LOQ: N/A | LOD: N/A LOQ: N/A | LOD: 0.20 LOQ: 0.65 | LOD: 0.42 LOQ: 1.35 |
Reported method26 | LOD: N/A LOQ: N/A | LOD: N/A LLOQ: 0.5 ng/mL | LOD: N/A LLOQ: 0.25 ng/mL | LOD: N/A LLOQ: 5.0 ng/mL | LOD: N/A LLOQ: 5.0 ng/mL |
Reported method30 | LOD: 0.92 LOQ: 2.60 | LOD: 0.42 LOQ: 1.07 | LOD: N/A LOQ: N/A | LOD: N/A LOQ: N/A | LOD: N/A LOQ: N/A |
Reported method33 | LOD: 1.45 LOQ: 4.40 | LOD: 0.50 LOQ: 1.51 | LOD: N/A LOQ: N/A | LOD: N/A LOQ: N/A | LOD: N/A LOQ: N/A |
