Table 7 Emission coefficients \(A_{{\nu ^{\prime } \nu ^{{\prime \prime }} }}\) (unit of s−1) and Franck–Condon factors \(f_{{\nu ^{\prime } \nu ^{{\prime \prime }} }}\) of the \(A{}^{2}\Sigma_{1/2}^{ + } X{}^{2}\Pi_{3/2}\) and \(X{}^{2}\Pi_{{{1}/2}} X{}^{2}\Pi_{3/2}\) transitions.
From: A theoretical investigation of spectroscopy properties and transition properties of TlBr+ cation
ν″ | \(A{}^{2}\Sigma_{1/2}^{ + } X{}^{2}\Pi_{3/2}\) | \(X{}^{2}\Pi_{{{1}/2}} X{}^{2}\Pi_{3/2}\) | ||||
|---|---|---|---|---|---|---|
ƒ0ν″ | A0ν″ | ΣA0 | ƒ0ν″ | A0ν″ | ΣA0 | |
0 | 9.751(− 1) | 6.250(− 1) | 6.304(− 1) | 7.879(− 1) | 4.206(3) | 5.888(3) |
1 | 4.713(− 3) | 2.539(− 3) | 5.772(− 2) | 4.385(2) | ||
2 | 4.081(− 5) | 4.148(− 5) | 1.048(− 2) | 9.112(1) | ||
3 | 7.727(− 7) | 7.589(− 7) | 1.748(− 3) | 1.675(1) | ||
4 | 2.580(− 8) | 1.725(− 7) | 3.470(− 4) | 3.527(0) | ||
5 | 1.582(− 8) | 5.286(− 8) | 7.995(− 5) | 8.193(− 1) | ||
