Table 3 Thermo-analytical data of hardened neat WOPC and hardened WOPC-MS pastes containing 0.75% MS after 7 and 28 days of hydration.

	Stage	Temp. range, °C	T^onset, °C	T^max, °C	W_loss, %	Rw₁₀₀₀, °C	R²	A, 1/s	E^a, kJ/mol	∆H^a, kJ/mol	∆S^a, J/mol.K	∆G^a, kJ/mol
Mix WMS0-7d	I	32–380	99	175	9.087	80.95	0.93	10.60	25.23	21.50	-228.725	123.97
	II	400–609	463	526	4.324		0.98	2.94 × 10¹⁰	183.03	176.38	-52.7186	218.50
	III	629–879	629	775	5.414		0.99	1.21 × 10⁰⁷	171.40	162.69	-119.772	288.21
	III	629–879	629	775	5.414		0.99	1.21 × 10⁰⁷	∑ 379.66	∑ 360.57	∑ -401.22	∑ 630.69
Mix WMS3-7d	I	24–386	100	127	8.87	80.60	0.93	2.99	19.67	16.36	-238.297	111.68
	II	472–576	472	509	3.668		0.98	2.61 × 10¹³	221.74	215.23	3.932746	212.16
	III	576–805	618	737	5.635		0.99	2.57 × 10⁰⁸	188.80	180.40	-94.0709	275.41
	III	576–805	618	737	5.635		0.99	2.57 × 10⁰⁸	∑ 430.22	∑ 412.00	∑ -328.44	∑ 599.25
Mix WMS0-28d	I	24–284	98	150	5.776	80.71	0.91	5.70	20.59	17.07	-233.408	115.80
	II	492–596	483	520	4.399		0.99	1.15 × 10¹²	204.56	197.97	-22.187	215.56
	III	596–929	608	753	6.98		0.98	271578.4	141.10	132.57	-151.196	287.69
	III	596–929	608	753	6.98		0.98	271578.4	∑ 366.25	∑ 347.61	∑ -406.79	∑ 619.06
Mix WMS3-28d	I	24–369	100	157	9.734	81.36	0.97	9.37	24.33	20.76	-229.406	119.40
	II	473–577	469	518	4.647		0.97	1.41 × 10¹³	219.98	213.40	-1.2992	214.43
	III	577–806	601	744	3.898		0.97	4.86 × 10¹⁶	353.53	345.08	64.34119	279.64
	III	577–806	601	744	3.898		0.97	4.86 × 10¹⁶	∑ 597.84	∑ 579.23	∑ -166.36	∑ 613.47

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