Table 7 The magnitudes of \({\Delta G}_{m,tr}^{0}\), \({\Delta H}_{m,tr}^{0}\), and \({\Delta S}_{m,tr}^{0}\) for the NaDS + (1.001 mmol kg–1) OFC mixed system in various aq. K-salts media.
Medium | Csalts (mmol kg−1) | T (K) | \({\Delta G}_{m,tr}^{0}\) (kJ mol−1) | \({\Delta H}_{m,tr}^{0}\) (kJ mol−1) | \({\Delta S}_{m,tr}^{0}\) (J mol−1 K−1) |
|---|---|---|---|---|---|
H2O + KCl | 5.011 | 298.15 | − 1.611 | 6.853 | 28.39 |
303.15 | − 1.919 | 4.765 | 22.05 | ||
308.15 | − 1.969 | 2.548 | 14.66 | ||
313.15 | − 1.612 | 0.247 | 5.938 | ||
318.15 | − 1.616 | − 2.210 | − 1.870 | ||
323.15 | − 1.225 | − 4.756 | − 10.93 | ||
H2O + KNO3 | 5.001 | 298.15 | − 1.514 | 6.488 | 26.84 |
303.15 | − 1.859 | 4.413 | 20.69 | ||
308.15 | − 1.885 | 2.203 | 13.27 | ||
313.15 | − 1.482 | − 0.091 | 4.442 | ||
318.15 | − 1.422 | − 2.540 | − 3.512 | ||
323.15 | − 1.011 | − 5.076 | − 12.58 | ||
H2O + KHSO4 | 4.999 | 298.15 | − 2.363 | 6.427 | 29.48 |
303.15 | − 2.657 | 4.319 | 23.01 | ||
308.15 | − 2.618 | 2.075 | 15.23 | ||
313.15 | − 2.380 | − 0.277 | 6.715 | ||
318.15 | − 2.254 | − 2.782 | − 1.659 | ||
323.15 | − 1.777 | − 5.377 | − 11.14 | ||
H2O + K2SO4 | 5.013 | 298.15 | − 1.803 | 5.742 | 25.31 |
303.15 | − 2.183 | 3.627 | 19.16 | ||
308.15 | − 2.223 | 1.380 | 11.69 | ||
313.15 | − 1.863 | − 0.952 | 2.909 | ||
318.15 | − 1.823 | − 3.439 | − 5.079 | ||
323.15 | − 1.446 | − 6.015 | − 14.14 |