Table 2 Kinetic model parameters for the photo-Fenton-like oxidation of PCT using the RTG-MIL-100(Fe)/H₂O₂/UV system.
Temp. K | Zero-order model | First-order model | Second-order model | ||||||
|---|---|---|---|---|---|---|---|---|---|
k0 (min-1) ×102 | t1/2 (min) | R2 | k1(min-1) ×102 | t1/2(min) | R2 | k2 (min-1) ×102 | t1/2(min) | R2 | |
301 | 8.39 | 58.97 | 0.88 | 4.49 | 15.43 | 0.95 | 1.48 | 6.81 | 0.80 |
313 | 8.23 | 61.21 | 0.79 | 3.30 | 20.99 | 0.95 | 2.00 | 4.97 | 0.83 |
323 | 8.43 | 59.75 | 0.81 | 3.07 | 25.42 | 0.92 | 1.49 | 6.67 | 0.83 |
333 | 8.08 | 62.34 | 0.72 | 3.58 | 19.31 | 0.94 | 3.30 | 3.00 | 0.87 |
