Abstract
Supercapacitors but suffer from low specific capacity and poor rate capability due to limited electrical conductivity. Herein, a zeolitic imidazolate framework (ZIF-67) was employed simultaneously as a cobalt source and a sacrificial template to direct the room-temperature hydrolysis of Ni²⁺ ions, leading to the formation of interwoven Co–Ni LDH nanosheets with enhanced electrolyte-electrode interaction and accelerated ion transport. Incorporation of carbon nanotubes (CNTs) markedly improved conductivity and charge-transfer kinetics, with the optimized CNC30 electrode delivering 870 F g⁻¹ at 1 A g⁻¹ and retaining 85% capacitance at 10 A g⁻¹. Electrochemical impedance spectroscopy confirmed a significant reduction in charge-transfer resistance from 1.37 Ω to 0.49 Ω upon CNT integration. Further enhancement was achieved by introducing ZIF-67, as CNCZ30 exhibited 902.7 F g⁻¹ at 1 A g⁻¹, with 72% retention at 10 A g⁻¹. Notably, CNCZ30 demonstrated excellent durability, maintaining 96.6% of its initial capacitance after 7000 cycles. These results highlight the synergistic effects of CNTs, LDHs, and ZIF-67 in boosting conductivity, active surface area, and redox activity, positioning Co–Ni LDH/CNT/ZIF-67 composites as promising electrodes for next-generation supercapacitors.
Data availability
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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Acknowledgements
This work was supported and funded by the Deanship of Scientific Research at Imam Mohammad Ibn Saud Islamic University (IMSIU) (grant number IMSIU-DDRSP2603).
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This work was supported and funded by the Deanship of Scientific Research at Imam Mohammad Ibn Saud Islamic University (IMSIU) (grant number IMSIU-DDRSP2603).
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Mariam Sh. Gohr, (Conceptualization; Visualization)Mohamed Abdel Rafea Konsow (Funding acquisition; Project administration; Supervision; Writing – review & editing)Wael Wazeer, (Conceptualization; Data curation; Methodology)Sara Gad, (Conceptualization; Formal analysis; Resources; Software; Writing –original draft)Diaa A Rayan, (Methodology; Resources; Validation)Mohamed H Eisa, (Investigation; Resources; Supervision; Validation)Huda F. Khalil, (Data curation; Formal analysis; Resources; Software; Writing –original draft; Writing – review & editing)
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Gohr, M.S., Rafea, M.A., Wazeer, W. et al. Hierarchical Co–Ni hydroxides integrated with carbon nanotubes via ZIF-67 templates for high-performance supercapacitors. Sci Rep (2026). https://doi.org/10.1038/s41598-026-42472-5
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DOI: https://doi.org/10.1038/s41598-026-42472-5