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Engineered cementitious composites with nano calcium carbonate and corona waste mask fibers for sustainable 3D printing applications
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  • Published: 13 March 2026

Engineered cementitious composites with nano calcium carbonate and corona waste mask fibers for sustainable 3D printing applications

  • A. R. Krishnaraja  ORCID: orcid.org/0000-0002-1521-19731,
  • P. Kulanthaivel  ORCID: orcid.org/0000-0002-8141-09032,
  • Arunkumar Manoharan3,
  • Suresh Muthusamy  ORCID: orcid.org/0000-0002-9156-20544,
  • Chandrakant Sonawane  ORCID: orcid.org/0000-0002-3408-50605,6,
  • Choon Kit Chan  ORCID: orcid.org/0000-0001-7478-73347 &
  • …
  • Md Irfanul Haque Siddiqui  ORCID: orcid.org/0000-0003-4289-48268 

Scientific Reports , Article number:  (2026) Cite this article

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We are providing an unedited version of this manuscript to give early access to its findings. Before final publication, the manuscript will undergo further editing. Please note there may be errors present which affect the content, and all legal disclaimers apply.

Subjects

  • Engineering
  • Materials science

Abstract

Engineered cementitious composites (ECC) are ductile cement-based materials developed to overcome the brittleness of conventional concrete by exhibiting strain-hardening behaviour and improved crack control under tensile loading. The use of waste polypropylene fibres obtained from discarded COVID-19 face masks offers a sustainable approach to enhancing ECC performance, while nano calcium carbonate (NCC), a comparatively economical nanomaterial, improves particle packing and interfacial bonding in cementitious systems. This study examines the combined influence of NCC and modified corona waste mask fibres (CWMF) on the fresh, physical, and mechanical properties of 3D printed cement-based mortar, with NCC incorporated in the range of 0–4% by weight of cement. The results show that increasing NCC content reduces fluidity but significantly improves the buildability of the mixes. The dry density of the 3D printed specimens increased up to an optimum NCC content of 3% and decreased thereafter, while water absorption exhibited a similar trend. Mechanical properties evaluated at the designated test age indicate that compressive, flexural, and splitting tensile strengths attained optimum values at 3% NCC. At this NCC level, the 3D printed specimens consistently demonstrated superior mechanical performance compared to conventionally cast samples, indicating the effectiveness of NCC–CWMF modified mixes for 3D concrete printing applications.

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Data availability

Data can be provided upon a reasonable request from the corresponding author Dr Chandrakant sonawane.

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Funding

Open access funding provided by Symbiosis International (Deemed University). The authors would like to acknowledge the funding from the Ongoing Research Funding Program, (ORF-2026-999), King Saud University, Riyadh, Saudi Arabia.

Author information

Authors and Affiliations

  1. Department of Civil Engineering, Kongu Engineering College (Autonomous), Perundurai, Erode, Tamil Nadu, India

    A. R. Krishnaraja

  2. Department of Civil Engineering, Nandha Engineering College, Perundurai, Erode, Tamil Nadu, India

    P. Kulanthaivel

  3. Department of Civil Engineering, Indian Institute of Technology Madras, Chennai, Tamil Nadu, India

    Arunkumar Manoharan

  4. Department of Electrical and Electronics Engineering, Kongu Engineering College (Autonomous), Perundurai, Erode, Tamil Nadu, India

    Suresh Muthusamy

  5. Symbiosis Institute of Technology, Pune Campus, Symbiosis International (Deemed University), Pune, India

    Chandrakant Sonawane

  6. Symbiosis Centre for Nanoscience and Nanotechnology, Symbiosis international (Deemed University), Pune, India

    Chandrakant Sonawane

  7. Faculty of Engineering and Quantity Surveying, INTI International University, 71800, Nilai, Negeri Sembilan, Malaysia

    Choon Kit Chan

  8. Department of Mechanical Engineering, College of Engineering, King Saud University, Riyadh, 12372, Saudi Arabia

    Md Irfanul Haque Siddiqui

Authors
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Contributions

A.R.K. conceived the research idea and supervised the overall study. P.K. contributed to methodology development and data curation. M.A.K. carried out the experimental investigations and prepared the initial draft of the manuscript. S.M. assisted with software implementation, validation, and technical editing. C.S. contributed to formal analysis and visualization. C.K.C. provided critical revisions, resources, and validation of results. M.I.H.S. contributed to the review, editing, and refinement of the manuscript. All authors discussed the results, reviewed the manuscript, and approved the final version.

Corresponding author

Correspondence to Chandrakant Sonawane.

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The authors declare no competing interests.

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Cite this article

Krishnaraja, A.R., Kulanthaivel, P., Manoharan, A. et al. Engineered cementitious composites with nano calcium carbonate and corona waste mask fibers for sustainable 3D printing applications. Sci Rep (2026). https://doi.org/10.1038/s41598-026-43424-9

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  • Received: 15 September 2025

  • Accepted: 04 March 2026

  • Published: 13 March 2026

  • DOI: https://doi.org/10.1038/s41598-026-43424-9

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Keywords

  • 3D printing
  • Nano calcium carbonate
  • Corona waste mask fibers
  • Buildability
  • Printability
  • Process innovation
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