Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

Advertisement

Scientific Reports
  • View all journals
  • Search
  • My Account Login
  • Content Explore content
  • About the journal
  • Publish with us
  • Sign up for alerts
  • RSS feed
  1. nature
  2. scientific reports
  3. articles
  4. article
Hydrothermal system dynamics at Pisciarelli fumarole field (Campi Flegrei): insights from geophysical and numerical modelling
Download PDF
Download PDF
  • Article
  • Open access
  • Published: 03 April 2026

Hydrothermal system dynamics at Pisciarelli fumarole field (Campi Flegrei): insights from geophysical and numerical modelling

  • Rosanna Salone1,2,
  • Antonio Troiano1,
  • Maria Giulia Di Giuseppe1,
  • Roberto Isaia1 &
  • …
  • Rosa Di Maio2 

Scientific Reports , Article number:  (2026) Cite this article

We are providing an unedited version of this manuscript to give early access to its findings. Before final publication, the manuscript will undergo further editing. Please note there may be errors present which affect the content, and all legal disclaimers apply.

Subjects

  • Environmental sciences
  • Solid Earth sciences

Abstract

The Pisciarelli fumarolic-hydrothermal area (Campi Flegrei caldera, Southern Italy), together with the adjacent Solfatara maar-diatreme, is a critical site due to the recent increase in volcanic activity. This includes very high CO2 fluxes (exceeding 600 tons/day), continuous morphological changes and frequent seismic events. This study aims to reconstruct the architecture and fluid dynamics of the Pisciarelli fumarole field by integrating geophysical imaging and thermo-fluid dynamic numerical modelling. A detailed 3D petrophysical model was developed from electrical resistivity, time-domain induced polarization and self-potential data, and was further constrained by existing volcanological and geochemical information. Thermodynamic simulations of a hot H2O-CO2 mixture circulating in the shallow hydrothermal system of Pisciarelli were carried out using the TOUGH2 numerical code with the EOS2 module. This modelling approach enabled detailed characterization of the system’s current dynamics, including temperature distribution, gas pressure, gas saturation levels, and fluid flow pathways. The results emphasize the pivotal role of the main fault system in controlling fluid accumulation and migration, which in turn drives the intense degassing activity observed at Pisciarelli. These findings provide new insights into the physical state of the Pisciarelli-Solfatara hydrothermal complex and contribute to assessing the potential for sudden explosive hydrothermal events under current conditions.

Data availability

All the parameters required to reproduce the numerical simulations are reported in the manuscript and Supplementary Information. Additional details on the model implementation can be provided by the corresponding author upon request.

References

  1. Giaccio, B., Hajdas, I., Isaia, R., Deino, A. & Nomade, S. High-precision 14C and 40Ar/39Ar dating of the Campanian Ignimbrite (Y-5) reconciles the time-scales of climatic-cultural processes at 40 ka. Sci. Rep. 7, 45940. https://doi.org/10.1038/srep45940 (2017).

    Google Scholar 

  2. Smith, V. C., Isaia, R. & Pearce, N. J. G. Tephrostratigraphy and glass compositions of post-15 kyr Campi Flegrei eruptions: implications for eruption history and chronostratigraphic markers. Quat Sci. Rev. 30 (25–26), 3638–3660. https://doi.org/10.1016/j.quascirev.2011.07.012 (2011).

    Google Scholar 

  3. Isaia, R. et al. Stratigraphy, structure, and volcano-tectonic evolution of Solfatara maar-diatreme (Campi Flegrei, Italy). Geol. Soc. Am. Bull. 127 (9–10), 1485–1504. https://doi.org/10.1130/B31183.1 (2015).

    Google Scholar 

  4. Troiano, A., Di Giuseppe, M. G. & Isaia, R. 3D structure of the Campi Flegrei caldera central sector reconstructed through short–period magnetotelluric imaging. Sci. Rep. 12 (20802). https://doi.org/10.1038/s41598-022-24998-6 (2022).

  5. Carlino, S., Pivetta, T. & Ricciardi, G. Campi Flegrei – Monitoraggio Geodetico: Rete Gravimetrica. In Bianco, F., Di Vito, M. A. & Castellano, M. (Eds.), Il Monitoraggio dei Vulcani Campani – 2022, 71–73 (2023). Available at: http://hdl.handle.net/2122/16623

  6. Orsi, G. et al. Short-term ground deformations and seismicity in the resurgent Campi Flegrei caldera (Italy): an example of active block-resurgence in a densely populated area. J. Volcanol Geoth Res. 91 (2–4), 415–451. https://doi.org/10.1016/S0377-0273(99)00050-5 (1999).

    Google Scholar 

  7. De Natale, G. et al. The Campi Flegrei caldera: unrest mechanisms and hazards. Geol. Soc. Lond. Spec. Publ. 269, 25–45. https://doi.org/10.1144/GSL.SP.2006.269.01.03 (2006).

    Google Scholar 

  8. D’Auria, L. et al. Repeated fluid-transfer episodes as a mechanism for the recent dynamics of Campi Flegrei caldera (1989–2010). J. Geophys. Res. 116, B04313. https://doi.org/10.1029/2010JB007837 (2011).

    Google Scholar 

  9. De Martino, P., Tammaro, U. & Obrizzo, F. GPS time series at Campi Flegrei caldera (2000-2013). Ann. Geophys. 57 (2), S0213. https://doi.org/10.4401/ag-6431 (2014).

    Google Scholar 

  10. INGV. Bollettini di sorveglianza dei Vulcani Campani. (2025). Retrieved from: http://www.ov.ingv.it/ov/bollettini-campi-flegrei

  11. Cardellini, C. et al. Monitoring diffuse volcanic degassing during volcanic unrests: The case of Campi Flegrei (Italy). Sci. Rep. 7 (6757). https://doi.org/10.1038/s41598-017-06941-2 (2017).

  12. Tamburello, G. et al. Escalating CO2 degassing at the Pisciarelli fumarolic system, and implications for the ongoing Campi Flegrei unrest. J. Volcanol Geoth Res. 384, 151–157. https://doi.org/10.1016/j.jvolgeores.2019.07.005 (2019).

    Google Scholar 

  13. Caliro, S. et al. Campi Flegrei – Monitoraggio Geochimico. In Di Vito, M. A. & Castellano, M. (Eds.), Il Monitoraggio dei Vulcani Campani – 2023, 101–119 (2024). Available at: https://www.earth-prints.org/handle/2122/57703

  14. Di Giuseppe, M. G. et al. Electrical resistivity tomography imaging of the near-surface structure of the Solfatara Crater, Campi Flegrei (Naples, Italy). Bull. Volcanol. 77, 27. https://doi.org/10.1007/s00445-015-0910-6 (2015).

  15. Isaia, R. et al. Volcano-tectonic setting of the Pisciarelli fumarole field, Campi Flegrei caldera, Southern Italy: insights into fluid circulation patterns and hazard scenarios. Tectonics 40, e2020TC006227. https://doi.org/10.1029/2020TC006227 (2021).

  16. Valentine, G. A., Graettinger, A. H. & Sonder, I. Explosion depths for phreatomagmatic eruptions. Geophys. Res. Lett. 41, 3045–3051. https://doi.org/10.1002/2014GL060096 (2014).

    Google Scholar 

  17. Caine, J. S., Evans, J. P. & Forster, C. B. Fault zone architecture and permeability structure. Geology 24, 1025–1028. https://doi.org/10.1130/0091-7613(1996)024%3C1025:FZAAPS%3E2.3.CO;2 (1996).

    Google Scholar 

  18. Reid, M. E., Sisson, T. W. & Brien, D. L. Volcano collapse promoted by hydrothermal alteration and edifice shape, Mount Rainier. Wash. Geology. 29 (9), 779–782 (2001).

    Google Scholar 

  19. Revil, A., Johnson, T. C. & Finizola, A. Three-dimensional resistivity tomography of Vulcan’s forge, Vulcano Island, Southern Italy. Geophys. Res. Lett. 37 (15). https://doi.org/10.1029/2010GL043983 (2010).

  20. Rouwet, D. et al. Recognizing and tracking volcanic hazards related to non-magmatic unrest: a review. J. App Volcanol. 3 (17). https://doi.org/10.1186/s13617-014-0017-3 (2014).

  21. Boudon, G., Balcone-Boissard, H., Villemant, B. & Morgan, D. J. What factors control superficial lava dome explosivity? Sci. Rep. 5 (14551). https://doi.org/10.1038/srep14551 (2015).

  22. Chiodini, G. et al. Long-term variations of the Campi Flegrei, Italy, volcanic system as revealed by the monitoring of hydrothermal activity. J. Geophys. Res. Solid Earth. 115, B03205. https://doi.org/10.1029/2008JB006258 (2010).

  23. Todesco, M., Rinaldi, A. P. & Bonafede, M. Modeling of unrest signals in heterogeneous hydrothermal systems. J. Geophys. Res. 115, B09213. https://doi.org/10.1029/2010JB007474 (2010).

    Google Scholar 

  24. Montanaro, C. et al. Experimental investigations on the explosivity of steam-driven eruptions: a case study of Solfatara volcano (Campi Flegrei). J. Geophys. Res. Solid Earth. 121. https://doi.org/10.1002/2016JB013273 (2016).

  25. Ingebritsen, S. E. & Sorey, M. L. Vapor-dominated zones within hydrothermal systems: evolution and natural state. J. Geophys. Res. Solid Earth. 93 (B11), 13635–13655. https://doi.org/10.1029/JB093iB11p13635 (1988).

    Google Scholar 

  26. Troiano, A., Di Giuseppe, M. G., Troise, C., Tramelli, A. & De Natale, G. A Coulomb stress model for induced seismicity distribution due to fluid injection and withdrawal in deep boreholes. Geophys. J. Int. 195 (1), 504–512. https://doi.org/10.1093/gji/ggt229 (2013).

    Google Scholar 

  27. Todesco, M., Rutqvist, J., Chiodini, G., Pruess, K. & Oldenburg, C. M. Modeling of recent volcanic episodes at Phlegrean Fields (Italy); geochemical variations and ground deformation. Geothermics 33, 531–547. https://doi.org/10.1016/j.geothermics.2003.08.014 (2004).

    Google Scholar 

  28. Rinaldi, A. P., Todesco, M. & Bonafede, M. Hydrothermal instability and ground displacement at the Campi Flegrei caldera. Phys. Earth Planet. Inter. 178, 155–161. https://doi.org/10.1016/j.pepi.2009.09.005 (2010).

    Google Scholar 

  29. Troiano, A., Di Giuseppe, M. G., Petrillo, Z., Troise, C. & De Natale, G. Ground deformation at calderas driven by fluid injection: modelling unrest episodes at Campi Flegrei (Italy). Geophys. J. Inter. 187 (2), 833–847. https://doi.org/10.1111/j.1365-246X.2011.05149.x (2011).

    Google Scholar 

  30. Petrillo, Z. et al. Defining a 3D physical model for the hydrothermal circulation at Campi Flegrei caldera (Italy). J. Volcanol Geoth Res. 264, 172–182. https://doi.org/10.1016/j.jvolgeores.2013.08.008 (2013).

    Google Scholar 

  31. Ingebritsen, S. E., Geiger, S., Hurwitz, S. & Driesner, T. Numerical simulation of magmatic hydrothermal systems. Rev. Geophys. 48 (1), RG1002. https://doi.org/10.1029/2009RG000287 (2010).

    Google Scholar 

  32. Pearson, S. C. P. et al. Integrated geophysical and hydrothermal models of flank degassing and fluid flow at Masaya volcano, Nicaragua. Geochem. Geophys. Geosyst. 13, Q05011. https://doi.org/10.1029/2012GC004117 (2012).

  33. Di Giuseppe, M. G. & Troiano, A. Monitoring active fumaroles through time-lapse electrical resistivity tomograms: an application to the Pisciarelli fumarolic field (Campi Flegrei, Italy). J. Volcanol Geoth Res. 375, 32–42. https://doi.org/10.1016/j.jvolgeores.2019.03.009 (2019).

    Google Scholar 

  34. Giudicepietro, F. et al. Insight into Campi Flegrei caldera unrest through seismic tremor measurements at Pisciarelli fumarolic field. Geochem. Geophys. Geosyst. 20, 5544–5555. https://doi.org/10.1029/2019GC008610 (2019).

    Google Scholar 

  35. Fedele, A. et al. Time-lapse landform monitoring in the Pisciarelli (Campi Flegrei-Italy) fumarole field using UAV photogrammetry. Rem. Sens. 13 (1), 118. https://doi.org/10.3390/rs13010118 (2020).

    Google Scholar 

  36. Troiano, A., Isaia, R., Di Giuseppe, M. G., Tramparulo, F. D. A. & Vitale, S. Deep electrical resistivity tomography for a 3D picture of the most active sector of Campi Flegrei caldera. Sci. Rep. 9 (1), 15124. https://doi.org/10.1038/s41598-019-51568-0 (2019).

    Google Scholar 

  37. Troiano, A., Isaia, R., Tramparulo, F. D. A. & Di Giuseppe, M. G. The Pisciarelli main fumarole mechanisms reconstructed by electrical resistivity and induced polarization imaging. Sci. c Rep. 11 (1), 18639. https://doi.org/10.1038/s41598-021-97413-1 (2021).

    Google Scholar 

  38. Pruess, K., Oldenburg, C. & Moridis, D. TOUGH2 User’s Guide Vol. –43134 (Berkeley, 1999).

  39. Pruess, K. The TOUGH Codes – A family of simulation tools for multiphase flow and transport processes in permeable media. Vadose Zone J. 3 (3), 738–746. https://doi.org/10.2136/vzj2004.0738 (2004).

    Google Scholar 

  40. Keenan, J. P., Keyes, F. G., Hill, P. G. & Moore, J. G. Steam Tables – Thermodynamic Properties of Water Including Vapor, Liquid, and Solid Phases pp. 162 (Wiley, 1969).

  41. G. Wolff, R. Physical properties of rocks; porosity, permeability, distribution coefficients, and dispersivity. U S Geol. Surv. Open-File Rep. 82–166 pp 123. https://doi.org/10.3133/ofr82166 (1982).

    Google Scholar 

  42. Neuzil, C. E. How permeable are clays and shales? Water Resour. Res. 30 (2), 145–150. https://doi.org/10.1029/93WR02930 (1994).

    Google Scholar 

  43. Waples, D. W. & Waples, J. S. A review and evaluation of specific heat capacities of rocks, minerals, and subsurface fluids. Part 1: minerals and nonporous rocks. Nat. Resour. Res. 13, 97–122. https://doi.org/10.1023/B:NARR.0000032647.41046.e7 (2004).

    Google Scholar 

  44. Dong, Y., McCartney, J. S. & Lu, N. Critical review of thermal conductivity models for unsaturated soils. Geotech. Geol. Eng. 33, 207–221. https://doi.org/10.1007/s10706-015-9843-2 (2015).

  45. Jasim, A., Whitaker, F. F. & Rust, A. C. Impact of channelized flow on temperature distribution and fluid flow in restless calderas: insight from Campi Flegrei caldera, Italy. J. Volcanol Geoth Res. 303, 157–174. https://doi.org/10.1016/j.jvolgeores.2015.07.029 (2015).

    Google Scholar 

  46. Mayer, K. et al. Hydrothermal alteration of surficial rocks at Solfatara (Campi Flegrei): Petrophysical properties and implications for phreatic eruption processes. J. Volcanol Geothe Res. 320, 128–143. https://doi.org/10.1016/j.jvolgeores.2016.04.020 (2016).

    Google Scholar 

  47. Chiodini, G., Caliro, S., De Martino, P., Avino, R. & Gherardi, F. Early signals of new volcanic unrest at Campi Flegrei caldera? Insights from geochemical data and physical simulations. Geology 40 (10), 943–946. https://doi.org/10.1130/G33251.1 (2012).

    Google Scholar 

  48. Caliro, S. et al. The origin of the fumaroles of La Solfatara (Campi Flegrei, South Italy). Geochim. Cosmochim. Acta. 71, 3040–3055. https://doi.org/10.1016/j.gca.2007.04.007 (2007).

    Google Scholar 

Download references

Funding

The authors declare that no funds, grants, or other support were received during the preparation of this manuscript.

Author information

Authors and Affiliations

  1. Istituto Nazionale di Geofisica e Vulcanologia, Osservatorio Vesuviano, Naples, 80124, Italy

    Rosanna Salone, Antonio Troiano, Maria Giulia Di Giuseppe & Roberto Isaia

  2. Dipartimento di Scienze della Terra, dell’Ambiente e delle Risorse, Università degli Studi di Napoli Federico II, Naples, 80126, Italy

    Rosanna Salone & Rosa Di Maio

Authors
  1. Rosanna Salone
    View author publications

    Search author on:PubMed Google Scholar

  2. Antonio Troiano
    View author publications

    Search author on:PubMed Google Scholar

  3. Maria Giulia Di Giuseppe
    View author publications

    Search author on:PubMed Google Scholar

  4. Roberto Isaia
    View author publications

    Search author on:PubMed Google Scholar

  5. Rosa Di Maio
    View author publications

    Search author on:PubMed Google Scholar

Contributions

R.S. developed and implemented the thermo-fluid dynamic numerical model, defined the initial and boundary conditions, and performed the TOUGH2 simulations. A.T. and M.G.D.G. coordinated the study and collaborated in the setup, execution, and analysis of the simulations. R.I. provided the geological and volcanological framework of the study area. R.D.M. contributed to the conceptualization and methodology of the research and was responsible for validation and supervision. All authors discussed the results and contributed to their interpretation and to the writing of the manuscript.

Corresponding author

Correspondence to Rosanna Salone.

Ethics declarations

Competing interests

The authors declare no competing interests.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary Material 1 (download DOCX )

Rights and permissions

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Salone, R., Troiano, A., Di Giuseppe, M.G. et al. Hydrothermal system dynamics at Pisciarelli fumarole field (Campi Flegrei): insights from geophysical and numerical modelling. Sci Rep (2026). https://doi.org/10.1038/s41598-026-46202-9

Download citation

  • Received: 03 November 2025

  • Accepted: 24 March 2026

  • Published: 03 April 2026

  • DOI: https://doi.org/10.1038/s41598-026-46202-9

Share this article

Anyone you share the following link with will be able to read this content:

Sorry, a shareable link is not currently available for this article.

Provided by the Springer Nature SharedIt content-sharing initiative

Keywords

  • Geophysical imaging
  • Thermo-fluid dynamic numerical simulations
  • Pisciarelli fumarolic-hydrothermal area
  • Campi Flegrei
Download PDF

Advertisement

Explore content

  • Research articles
  • News & Comment
  • Collections
  • Subjects
  • Follow us on Facebook
  • Follow us on X
  • Sign up for alerts
  • RSS feed

About the journal

  • About Scientific Reports
  • Contact
  • Journal policies
  • Guide to referees
  • Calls for Papers
  • Editor's Choice
  • Journal highlights
  • Open Access Fees and Funding

Publish with us

  • For authors
  • Language editing services
  • Open access funding
  • Submit manuscript

Search

Advanced search

Quick links

  • Explore articles by subject
  • Find a job
  • Guide to authors
  • Editorial policies

Scientific Reports (Sci Rep)

ISSN 2045-2322 (online)

nature.com footer links

About Nature Portfolio

  • About us
  • Press releases
  • Press office
  • Contact us

Discover content

  • Journals A-Z
  • Articles by subject
  • protocols.io
  • Nature Index

Publishing policies

  • Nature portfolio policies
  • Open access

Author & Researcher services

  • Reprints & permissions
  • Research data
  • Language editing
  • Scientific editing
  • Nature Masterclasses
  • Research Solutions

Libraries & institutions

  • Librarian service & tools
  • Librarian portal
  • Open research
  • Recommend to library

Advertising & partnerships

  • Advertising
  • Partnerships & Services
  • Media kits
  • Branded content

Professional development

  • Nature Awards
  • Nature Careers
  • Nature Conferences

Regional websites

  • Nature Africa
  • Nature China
  • Nature India
  • Nature Japan
  • Nature Middle East
  • Privacy Policy
  • Use of cookies
  • Legal notice
  • Accessibility statement
  • Terms & Conditions
  • Your US state privacy rights
Springer Nature

© 2026 Springer Nature Limited

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing