Abstract
The Pisciarelli fumarolic-hydrothermal area (Campi Flegrei caldera, Southern Italy), together with the adjacent Solfatara maar-diatreme, is a critical site due to the recent increase in volcanic activity. This includes very high CO2 fluxes (exceeding 600 tons/day), continuous morphological changes and frequent seismic events. This study aims to reconstruct the architecture and fluid dynamics of the Pisciarelli fumarole field by integrating geophysical imaging and thermo-fluid dynamic numerical modelling. A detailed 3D petrophysical model was developed from electrical resistivity, time-domain induced polarization and self-potential data, and was further constrained by existing volcanological and geochemical information. Thermodynamic simulations of a hot H2O-CO2 mixture circulating in the shallow hydrothermal system of Pisciarelli were carried out using the TOUGH2 numerical code with the EOS2 module. This modelling approach enabled detailed characterization of the system’s current dynamics, including temperature distribution, gas pressure, gas saturation levels, and fluid flow pathways. The results emphasize the pivotal role of the main fault system in controlling fluid accumulation and migration, which in turn drives the intense degassing activity observed at Pisciarelli. These findings provide new insights into the physical state of the Pisciarelli-Solfatara hydrothermal complex and contribute to assessing the potential for sudden explosive hydrothermal events under current conditions.
Data availability
All the parameters required to reproduce the numerical simulations are reported in the manuscript and Supplementary Information. Additional details on the model implementation can be provided by the corresponding author upon request.
References
Giaccio, B., Hajdas, I., Isaia, R., Deino, A. & Nomade, S. High-precision 14C and 40Ar/39Ar dating of the Campanian Ignimbrite (Y-5) reconciles the time-scales of climatic-cultural processes at 40 ka. Sci. Rep. 7, 45940. https://doi.org/10.1038/srep45940 (2017).
Smith, V. C., Isaia, R. & Pearce, N. J. G. Tephrostratigraphy and glass compositions of post-15 kyr Campi Flegrei eruptions: implications for eruption history and chronostratigraphic markers. Quat Sci. Rev. 30 (25–26), 3638–3660. https://doi.org/10.1016/j.quascirev.2011.07.012 (2011).
Isaia, R. et al. Stratigraphy, structure, and volcano-tectonic evolution of Solfatara maar-diatreme (Campi Flegrei, Italy). Geol. Soc. Am. Bull. 127 (9–10), 1485–1504. https://doi.org/10.1130/B31183.1 (2015).
Troiano, A., Di Giuseppe, M. G. & Isaia, R. 3D structure of the Campi Flegrei caldera central sector reconstructed through short–period magnetotelluric imaging. Sci. Rep. 12 (20802). https://doi.org/10.1038/s41598-022-24998-6 (2022).
Carlino, S., Pivetta, T. & Ricciardi, G. Campi Flegrei – Monitoraggio Geodetico: Rete Gravimetrica. In Bianco, F., Di Vito, M. A. & Castellano, M. (Eds.), Il Monitoraggio dei Vulcani Campani – 2022, 71–73 (2023). Available at: http://hdl.handle.net/2122/16623
Orsi, G. et al. Short-term ground deformations and seismicity in the resurgent Campi Flegrei caldera (Italy): an example of active block-resurgence in a densely populated area. J. Volcanol Geoth Res. 91 (2–4), 415–451. https://doi.org/10.1016/S0377-0273(99)00050-5 (1999).
De Natale, G. et al. The Campi Flegrei caldera: unrest mechanisms and hazards. Geol. Soc. Lond. Spec. Publ. 269, 25–45. https://doi.org/10.1144/GSL.SP.2006.269.01.03 (2006).
D’Auria, L. et al. Repeated fluid-transfer episodes as a mechanism for the recent dynamics of Campi Flegrei caldera (1989–2010). J. Geophys. Res. 116, B04313. https://doi.org/10.1029/2010JB007837 (2011).
De Martino, P., Tammaro, U. & Obrizzo, F. GPS time series at Campi Flegrei caldera (2000-2013). Ann. Geophys. 57 (2), S0213. https://doi.org/10.4401/ag-6431 (2014).
INGV. Bollettini di sorveglianza dei Vulcani Campani. (2025). Retrieved from: http://www.ov.ingv.it/ov/bollettini-campi-flegrei
Cardellini, C. et al. Monitoring diffuse volcanic degassing during volcanic unrests: The case of Campi Flegrei (Italy). Sci. Rep. 7 (6757). https://doi.org/10.1038/s41598-017-06941-2 (2017).
Tamburello, G. et al. Escalating CO2 degassing at the Pisciarelli fumarolic system, and implications for the ongoing Campi Flegrei unrest. J. Volcanol Geoth Res. 384, 151–157. https://doi.org/10.1016/j.jvolgeores.2019.07.005 (2019).
Caliro, S. et al. Campi Flegrei – Monitoraggio Geochimico. In Di Vito, M. A. & Castellano, M. (Eds.), Il Monitoraggio dei Vulcani Campani – 2023, 101–119 (2024). Available at: https://www.earth-prints.org/handle/2122/57703
Di Giuseppe, M. G. et al. Electrical resistivity tomography imaging of the near-surface structure of the Solfatara Crater, Campi Flegrei (Naples, Italy). Bull. Volcanol. 77, 27. https://doi.org/10.1007/s00445-015-0910-6 (2015).
Isaia, R. et al. Volcano-tectonic setting of the Pisciarelli fumarole field, Campi Flegrei caldera, Southern Italy: insights into fluid circulation patterns and hazard scenarios. Tectonics 40, e2020TC006227. https://doi.org/10.1029/2020TC006227 (2021).
Valentine, G. A., Graettinger, A. H. & Sonder, I. Explosion depths for phreatomagmatic eruptions. Geophys. Res. Lett. 41, 3045–3051. https://doi.org/10.1002/2014GL060096 (2014).
Caine, J. S., Evans, J. P. & Forster, C. B. Fault zone architecture and permeability structure. Geology 24, 1025–1028. https://doi.org/10.1130/0091-7613(1996)024%3C1025:FZAAPS%3E2.3.CO;2 (1996).
Reid, M. E., Sisson, T. W. & Brien, D. L. Volcano collapse promoted by hydrothermal alteration and edifice shape, Mount Rainier. Wash. Geology. 29 (9), 779–782 (2001).
Revil, A., Johnson, T. C. & Finizola, A. Three-dimensional resistivity tomography of Vulcan’s forge, Vulcano Island, Southern Italy. Geophys. Res. Lett. 37 (15). https://doi.org/10.1029/2010GL043983 (2010).
Rouwet, D. et al. Recognizing and tracking volcanic hazards related to non-magmatic unrest: a review. J. App Volcanol. 3 (17). https://doi.org/10.1186/s13617-014-0017-3 (2014).
Boudon, G., Balcone-Boissard, H., Villemant, B. & Morgan, D. J. What factors control superficial lava dome explosivity? Sci. Rep. 5 (14551). https://doi.org/10.1038/srep14551 (2015).
Chiodini, G. et al. Long-term variations of the Campi Flegrei, Italy, volcanic system as revealed by the monitoring of hydrothermal activity. J. Geophys. Res. Solid Earth. 115, B03205. https://doi.org/10.1029/2008JB006258 (2010).
Todesco, M., Rinaldi, A. P. & Bonafede, M. Modeling of unrest signals in heterogeneous hydrothermal systems. J. Geophys. Res. 115, B09213. https://doi.org/10.1029/2010JB007474 (2010).
Montanaro, C. et al. Experimental investigations on the explosivity of steam-driven eruptions: a case study of Solfatara volcano (Campi Flegrei). J. Geophys. Res. Solid Earth. 121. https://doi.org/10.1002/2016JB013273 (2016).
Ingebritsen, S. E. & Sorey, M. L. Vapor-dominated zones within hydrothermal systems: evolution and natural state. J. Geophys. Res. Solid Earth. 93 (B11), 13635–13655. https://doi.org/10.1029/JB093iB11p13635 (1988).
Troiano, A., Di Giuseppe, M. G., Troise, C., Tramelli, A. & De Natale, G. A Coulomb stress model for induced seismicity distribution due to fluid injection and withdrawal in deep boreholes. Geophys. J. Int. 195 (1), 504–512. https://doi.org/10.1093/gji/ggt229 (2013).
Todesco, M., Rutqvist, J., Chiodini, G., Pruess, K. & Oldenburg, C. M. Modeling of recent volcanic episodes at Phlegrean Fields (Italy); geochemical variations and ground deformation. Geothermics 33, 531–547. https://doi.org/10.1016/j.geothermics.2003.08.014 (2004).
Rinaldi, A. P., Todesco, M. & Bonafede, M. Hydrothermal instability and ground displacement at the Campi Flegrei caldera. Phys. Earth Planet. Inter. 178, 155–161. https://doi.org/10.1016/j.pepi.2009.09.005 (2010).
Troiano, A., Di Giuseppe, M. G., Petrillo, Z., Troise, C. & De Natale, G. Ground deformation at calderas driven by fluid injection: modelling unrest episodes at Campi Flegrei (Italy). Geophys. J. Inter. 187 (2), 833–847. https://doi.org/10.1111/j.1365-246X.2011.05149.x (2011).
Petrillo, Z. et al. Defining a 3D physical model for the hydrothermal circulation at Campi Flegrei caldera (Italy). J. Volcanol Geoth Res. 264, 172–182. https://doi.org/10.1016/j.jvolgeores.2013.08.008 (2013).
Ingebritsen, S. E., Geiger, S., Hurwitz, S. & Driesner, T. Numerical simulation of magmatic hydrothermal systems. Rev. Geophys. 48 (1), RG1002. https://doi.org/10.1029/2009RG000287 (2010).
Pearson, S. C. P. et al. Integrated geophysical and hydrothermal models of flank degassing and fluid flow at Masaya volcano, Nicaragua. Geochem. Geophys. Geosyst. 13, Q05011. https://doi.org/10.1029/2012GC004117 (2012).
Di Giuseppe, M. G. & Troiano, A. Monitoring active fumaroles through time-lapse electrical resistivity tomograms: an application to the Pisciarelli fumarolic field (Campi Flegrei, Italy). J. Volcanol Geoth Res. 375, 32–42. https://doi.org/10.1016/j.jvolgeores.2019.03.009 (2019).
Giudicepietro, F. et al. Insight into Campi Flegrei caldera unrest through seismic tremor measurements at Pisciarelli fumarolic field. Geochem. Geophys. Geosyst. 20, 5544–5555. https://doi.org/10.1029/2019GC008610 (2019).
Fedele, A. et al. Time-lapse landform monitoring in the Pisciarelli (Campi Flegrei-Italy) fumarole field using UAV photogrammetry. Rem. Sens. 13 (1), 118. https://doi.org/10.3390/rs13010118 (2020).
Troiano, A., Isaia, R., Di Giuseppe, M. G., Tramparulo, F. D. A. & Vitale, S. Deep electrical resistivity tomography for a 3D picture of the most active sector of Campi Flegrei caldera. Sci. Rep. 9 (1), 15124. https://doi.org/10.1038/s41598-019-51568-0 (2019).
Troiano, A., Isaia, R., Tramparulo, F. D. A. & Di Giuseppe, M. G. The Pisciarelli main fumarole mechanisms reconstructed by electrical resistivity and induced polarization imaging. Sci. c Rep. 11 (1), 18639. https://doi.org/10.1038/s41598-021-97413-1 (2021).
Pruess, K., Oldenburg, C. & Moridis, D. TOUGH2 User’s Guide Vol. –43134 (Berkeley, 1999).
Pruess, K. The TOUGH Codes – A family of simulation tools for multiphase flow and transport processes in permeable media. Vadose Zone J. 3 (3), 738–746. https://doi.org/10.2136/vzj2004.0738 (2004).
Keenan, J. P., Keyes, F. G., Hill, P. G. & Moore, J. G. Steam Tables – Thermodynamic Properties of Water Including Vapor, Liquid, and Solid Phases pp. 162 (Wiley, 1969).
G. Wolff, R. Physical properties of rocks; porosity, permeability, distribution coefficients, and dispersivity. U S Geol. Surv. Open-File Rep. 82–166 pp 123. https://doi.org/10.3133/ofr82166 (1982).
Neuzil, C. E. How permeable are clays and shales? Water Resour. Res. 30 (2), 145–150. https://doi.org/10.1029/93WR02930 (1994).
Waples, D. W. & Waples, J. S. A review and evaluation of specific heat capacities of rocks, minerals, and subsurface fluids. Part 1: minerals and nonporous rocks. Nat. Resour. Res. 13, 97–122. https://doi.org/10.1023/B:NARR.0000032647.41046.e7 (2004).
Dong, Y., McCartney, J. S. & Lu, N. Critical review of thermal conductivity models for unsaturated soils. Geotech. Geol. Eng. 33, 207–221. https://doi.org/10.1007/s10706-015-9843-2 (2015).
Jasim, A., Whitaker, F. F. & Rust, A. C. Impact of channelized flow on temperature distribution and fluid flow in restless calderas: insight from Campi Flegrei caldera, Italy. J. Volcanol Geoth Res. 303, 157–174. https://doi.org/10.1016/j.jvolgeores.2015.07.029 (2015).
Mayer, K. et al. Hydrothermal alteration of surficial rocks at Solfatara (Campi Flegrei): Petrophysical properties and implications for phreatic eruption processes. J. Volcanol Geothe Res. 320, 128–143. https://doi.org/10.1016/j.jvolgeores.2016.04.020 (2016).
Chiodini, G., Caliro, S., De Martino, P., Avino, R. & Gherardi, F. Early signals of new volcanic unrest at Campi Flegrei caldera? Insights from geochemical data and physical simulations. Geology 40 (10), 943–946. https://doi.org/10.1130/G33251.1 (2012).
Caliro, S. et al. The origin of the fumaroles of La Solfatara (Campi Flegrei, South Italy). Geochim. Cosmochim. Acta. 71, 3040–3055. https://doi.org/10.1016/j.gca.2007.04.007 (2007).
Funding
The authors declare that no funds, grants, or other support were received during the preparation of this manuscript.
Author information
Authors and Affiliations
Contributions
R.S. developed and implemented the thermo-fluid dynamic numerical model, defined the initial and boundary conditions, and performed the TOUGH2 simulations. A.T. and M.G.D.G. coordinated the study and collaborated in the setup, execution, and analysis of the simulations. R.I. provided the geological and volcanological framework of the study area. R.D.M. contributed to the conceptualization and methodology of the research and was responsible for validation and supervision. All authors discussed the results and contributed to their interpretation and to the writing of the manuscript.
Corresponding author
Ethics declarations
Competing interests
The authors declare no competing interests.
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Salone, R., Troiano, A., Di Giuseppe, M.G. et al. Hydrothermal system dynamics at Pisciarelli fumarole field (Campi Flegrei): insights from geophysical and numerical modelling. Sci Rep (2026). https://doi.org/10.1038/s41598-026-46202-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/s41598-026-46202-9