Fig. 1: Selected family of 2D materials and their bandgaps.
From: Bandgap engineering of two-dimensional semiconductor materials

2D materials are chosen for their experimental significance and demonstration, with depictions of a perspective view of their crystal structures. Arrangement is in accordance with their bandgap, guided by the bottom wavelength/bandgap scale, whereas the bar beneath each structure indicates bandgap range from bulk to monolayer. Typically, the bulk bandgap is smaller than that of its monolayer (black bars), but there are exceptions (red bars). 2D materials on the far left, indicated by a gray box, are zero or near-zero bandgap, metallic, or semimetallic.