Author Correction: Pentamethylcyclopentadienyl rhodium(iii)–chiral disulfonate hybrid catalysis for enantioselective C–H bond functionalization

Correction to: Nature Catalysis https://doi.org/10.1038/s41929-018-0106-5, published online 23 July 2018.

In the version of this Article originally published, four important papers for transition metal/chiral anion asymmetric catalysis and 1,1'-binaphthyl-2,2'-disulfonate (BINSate) were erroneously omitted. These have now been added into the reference list at numbers 33, 43, 57 and 58, and the list renumbered accordingly:

33.Mahlau M. & List B. Asymmetric counteranion‐directed catalysis: Concept, definition, and applications. Angew. Chem. Int. Ed. 52, 518–533 (2013).

43.Pan S. C. & List B. The catalytic acylcyanation of imines. Chem. Asian J. 3, 430–437 (2008).

57.Mukherjee S. & List B. Chiral counteranions in asymmetric transition-metal catalysis: Highly enantioselective Pd/Brønsted acid-catalyzed direct α-allylation of aldehydes. J. Am. Chem. Soc. 129, 11336–11337 (2007).

58.Mayer S. & List B. Asymmetric counteranion‐directed catalysis. Angew. Chem. Int. Ed. 45, 4193–4195 (2006).

The text has been amended to include citations to these references as follows:

“Hybridization of organocatalysts with transition metals is an emerging method in asymmetric catalysis^31–35” now includes the new ref. 33: “Hybridization of organocatalysts with transition metals is an emerging method in asymmetric catalysis^31–36”.

“In this Article, we report the enantioselective conjugate addition of aromatic C–H bonds to α,β-unsaturated ketones catalysed by Cp*Rh(iii)/BINSate^42,43 (BINSate = 1,1'-binaphthyl-2,2'-disulfonate) (Fig. 1d)” now includes the new ref. 43: “In this Article, we report the enantioselective conjugate addition of aromatic C–H bonds to α,β-unsaturated ketones catalysed by Cp*Rh(iii)/BINSate^43–45 (BINSate = 1,1'-binaphthyl-2,2'-disulfonate) (Fig. 1d)”.

“The combination of a chiral anion and a cationic metal catalyst is an established catalytic system, especially in gold(i) catalysis^32,54” now includes the new refs 33, 57 and 58: “The combination of a chiral anion and a cationic metal catalyst is an established catalytic system, especially in gold(i) and palladium catalyses^{32,33,56–58}”.