Electrocatalysts enable the efficient interconversion of electrical and chemical energy for the sustainable production of fuels and chemicals. Here we highlight the importance of developing electrochemical adsorption isotherms to demystify complex reaction mechanisms and rationalize catalytic activity.
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References
Eliaz, N. & Gileadi, E. Physical Electrochemistry: Fundamentals, Techniques, and Applications (Wiley, 2019).
Chorkendorff, I. & Niemantsverdriet, J. W. Concepts of Modern Catalysis and Kinetics (Wiley, 2017).
Jung, O., Jackson, M. N., Bisbey, R. P., Kogan, N. E. & Surendranath, Y. Joule 6, 476–493 (2022).
Lucky, C. & Schreier, M. ACS Nano 18, 6008–6015 (2024).
Gileadi, E. Electrochim. Acta 32, 221–229 (1987).
Wesley, T. S., Román-Leshkov, Y. & Surendranath, Y. ACS Cent. Sci. 7, 1045–1055 (2021).
Moss, B. et al. J. Am. Chem. Soc. 146, 8915–8927 (2024).
Kuo, D.-Y. et al. J. Am. Chem. Soc. 140, 17597–17605 (2018).
Liang, C. et al. Nat. Catal. 7, 763–775 (2024).
Mayer, J. M. J. Am. Chem. Soc. 145, 7050–7064 (2023).
Kim, C. et al. ACS Catal. 14, 3128–3138 (2024).
Zhan, C. et al. ACS Catal. 11, 7694–7701 (2021).
Chang, X., Xiong, H., Lu, Q. & Xu, B. JACS Au. 3, 2948–2963 (2023).
Mayer, J. M. J. Catal. 439, 115725 (2024).
Shannon, S. L. & Goodwin, J. G. Jr Chem. Rev. 95, 677–695 (1995).
Snitkoff-Sol, R. Z., Bond, A. M. & Elbaz, L. ACS Catal. 14, 7576–7588 (2024).
Kastlunger, G. et al. ACS Catal. 12, 4344–4357 (2022).
Gao, G. & Wang, L.-W. Chem. Catal. 1, 1331–1345 (2021).
Acknowledgements
This work was performed under the auspices of the United States Department of Energy by Lawrence Livermore National Laboratory (LLNL) under contract DE-AC52-07NA27344. N.G. acknowledges support from a startup grant at NTU (award number 024462-00001). C.H. acknowledges support as part of the Center for Closing the Carbon Cycle, an Energy Frontier Research Center funded by the United States Department of Energy, Office of Science, Basic Energy Sciences under award number DE-SC0023427. Y.S. acknowledges the United States Department of Energy, Basic Energy Sciences award number DE-SC0020973. The authors thank J. Cataldo from Lawrence Livermore National Laboratory’s Program Development Support Office for assistance with graphic design. The authors also thank N. Razdan for his comments on the manuscript. Manuscript released as LLNL-JRNL-2003233.
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N.G. and A.T.C. contributed equally to this work. N.G., A.T.C. and Y.S. conceived the idea and wrote the manuscript with input from C.H.
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Nature Catalysis thanks Jason Bates and the other, anonymous, reviewer(s) for their contribution to the peer review of this work.
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Govindarajan, N., Chu, A.T., Hahn, C. et al. The overlooked role of adsorption isotherms in electrocatalysis. Nat Catal 8, 1254–1259 (2025). https://doi.org/10.1038/s41929-025-01461-z
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DOI: https://doi.org/10.1038/s41929-025-01461-z
