Aqueous sulfur-based redox flow batteries (SRFBs) are promising candidates for large-scale energy storage, yet the gap between the required and currently achievable performance has plagued their practical applications. Here, we propose several engineering strategies towards SRFB commercialization.
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References
Lei, J. et al. An active and durable molecular catalyst for aqueous polysulfide-based redox flow batteries. Nat. Energy 8, 1355–1364 (2023).
Li, Z. & Lu, Y. Polysulfide-based redox flow batteries with long life and low levelized cost enabled by charge-reinforced ion-selective membranes. Nat. Energy 6, 517–528 (2021).
Xia, Y. et al. A cost-effective alkaline polysulfide-air redox flow battery enabled by a dual-membrane cell architecture. Nat. Commun. 13, 2388 (2022).
Li, Z. et al. Air-breathing aqueous sulfur flow battery for ultralow-cost long duration electrical storage. Joule 1, 306–327 (2017).
Liu, J. et al. Sulfur-based aqueous batteries: electrochemistry and strategies. J. Am. Chem. Soc. 143, 15475–15489 (2021).
Li, Z., Weng, G., Zou, Q., Cong, G. & Lu, Y.-C. A high-energy and low-cost polysulfide/iodide redox flow battery. Nano Energy 30, 283–292 (2016).
Remick, R. & Ang, P. Electrically rechargeable anionically active reduction-oxidation electrical storage-supply system. US patent US4485154A (1984).
Ding, M. et al. A stable and energy-dense polysulfide/permanganate flow battery. ACS Nano 17, 16252–16263 (2023).
Gross, M. M. & Manthiram, A. Long-life polysulfide-polyhalide batteries with a mediator-ion solid electrolyte. ACS App. Energ. Mater. 2, 3445–3451 (2019).
Ma, D. et al. Highly active nanostructured CoS2/CoS heterojunction electrocatalysts for aqueous polysulfide/iodide redox flow batteries. Nat. Commun. 10, 3367 (2019).
Acknowledgements
The authors acknowledge the financial support from the National Key R&D Program of China (2024YFE0101100), the National Natural Science Foundation of China (U24A2060, 22088101, 22279023, and 22309031), and Science and Technology Commission of Shanghai Municipality (2024ZDSYS02).
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Zhang, J., Zhou, W., Zhao, D. et al. Aqueous sulfur-based redox flow battery. Nat Rev Electr Eng 2, 215–217 (2025). https://doi.org/10.1038/s44287-025-00153-x
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DOI: https://doi.org/10.1038/s44287-025-00153-x