Table 2 Comparison of rates and TOFs

From: New route toward building active ruthenium nanoparticles on ordered mesoporous carbons with extremely high stability

Materials

Ru loadings (wt%)

LA conversiona (%)

GVL yield (%)

Specific rate (molLAh−1gmetal−1)

TOFb (h−1)

OMC

0

3.4

-

-

-

0.1%Ru-OMC

0.3

7.8

6.6

34.7

3510

0.5%Ru-OMC

1.0

21.9

19.7

30.3

3061

1.5%Ru-OMC

3.7

72.1

65.9

28.0

2827

3.0%Ru-OMC

6.1

99.4

98.8

23.3

2351

6.0%Ru-OMC

12.6

97.4

96.9

11.1

1119

3.0%Ru-OMSC

4.8

39.2

36.4

11.9

1197

3.0%Ru-C

5.5

33.5

-

8.7

882

commercial Ru/C

5.0

48.3

30.3

13.9

1403

  1. aReaction conditions: LA 5.0 g, catalyst amount 0.3 wt%, H2 pressure 4.5 MPa, temperature 150°C and duration 2 h.
  2. bTOF, h−1: (turnover frequency) moles of substrate converted per mole of metal per hour.
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