Table 1 The relaxed surface areas, dangling bonds of Co2+ and Co3+ ions and surface energies of {100}, {110}, {111} and {112} crystal planes

From: Single Crystalline Co3O4 Nanocrystals Exposed with Different Crystal Planes for Li-O2 Batteries

Crystal planes

Relaxed surface area (Ã…2)

Dangling bonds of Co2+ ions number

Dangling bonds of Co3+ ions number

Density of dangling bonds of Co2+ ions (Å−2)

Density of dangling bonds of Co3+ ions (Å−2)

Total density of dangling bonds (Å−2)

Surface energy (J m−2)

{100}

34.13

2

2

6.13

6.13

12.27

0.92

{110}

47.96

2

4

4.34

8.68

13.02

1.31

{111}

33.11

0

9

0

27.70

27.70

2.31

{112}

83.23

3

9

3.75

11.26

15.02

1.46