Table 3 Mössbauer fitting parameters for Fe06-glu (the isomer shift values are referred to standard iron at r.t.).

From: New materials for Li-ion batteries: synthesis and spectroscopic characterization of Li2(FeMnCo)SiO4 cathode materials

 

Fe(II)

Fe(III)

FeCo

#1

#2

#3

#1

#1

#2

〈δ〉i

0.965(1)

0.990(4)

0.9(2)

0.24(1)

0.012(7)

0.5(2)

〈Δ〉i

2.445(1)

2.74(2)

2.2(5)

0.96(2)

0.02(1)

≈1.5

〈B〉i

    

32.57(5)

≈3

t i

5.90(8)

0.42(6)

0.2(1)

1.62(4)

0.26(1)

0.3(1)

σι

≈0

0.04(1)

0.3(1)

0.174(4)

0.06(2)

≈0

σι(B)

    

0.7(1)

≈10

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