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Showing 1–2 of 2 results
Advanced filters: Author: Agamemnon E. Crumpton Clear advanced filters

  • The chemistry of beryllium, one of the periodic table’s lightest elements, remains poorly understood. Now, a nucleophilic beryllium complex with a highly polarized Be–Be bond has been prepared—this compound could be seen as a mixed-oxidation state Be(0)/Be(II) complex. The Be–Be bond is cleaved upon reaction with an organic substrate.

    • Josef T. Boronski
    • Agamemnon E. Crumpton
    • Simon Aldridge
    ResearchOpen Access
    Nature Chemistry
    Volume: 16, P: 1295-1300

  • Calcium difluoride is a source of fluorochemicals, but the reactivity of Ca–F moieties is not well understood. Now a library of molecular Ca–F complexes featuring unique structural motifs has been synthesized, including via fluorochemical defluorination. Studies of mono- and dinuclear systems provided structure–activity relationships for E–F bond formation.

    • Job J. C. Struijs
    • Mathias A. Ellwanger
    • Simon Aldridge
    ResearchOpen Access
    Nature Chemistry
    Volume: 16, P: 1473-1480