Superconductivity and magnetic order are well known in C60 compounds of the form A3C60 (where A = alkali metal). The spherical C60 molecular ions in these crystals are almost always arranged in a face-centred cubic (f.c.c.) packing, except in Cs3C60, where the known superconducting phase has a body-centred cubic (b.c.c) packing. Now the f.c.c. polymorph for Cs3C60 has been isolated; it too is superconducting, although its magnetic properties are very different to those of its b.c.c counterpart.
- Alexey Y. Ganin
- Yasuhiro Takabayashi
- Kosmas Prassides