Well-defined and stable nanomicelles (20−30 nm in diameter) were demonstrated for the first time by the self-assembly of amphiphilic brush (comb-like) cyclic and tadpole-shaped copolymers based on a poly(glycidyl ether) backbone. In particular, the brush cyclic topology formed the most compact and most stable nanomicelles with an extremely narrow (pseudo-monodisperse) size distribution, which are unattainable by other conventional means. This study provides a unique opportunity for designing advanced functional high-performance amphiphile materials for micelles and facilitating their applications in various fields.
- Brian J Ree
- Yusuke Satoh
- Moonhor Ree
