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Showing 1–2 of 2 results
Advanced filters: Author: Brian M. Rotermund Clear advanced filters

  • Although the trivalent actinides are similar to the lanthanide series in terms of chemistry and bonding, their structures and properties can diverge significantly. Here, the authors report a series of complexes of the trivalent actinides Np(III) through Cf(III) along with their lanthanide counterparts using a polarizable non-innocent, sulfur-donor ligand.

    • Nicholas B. Beck
    • Cristian Celis-Barros
    • Thomas E. Albrecht
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-11

  • Californium is difficult to prepare in its divalent state. Now, crystals of a Cf(II) crown–ether complex have been synthesized by reduction of a Cf(III) precursor with an Al/Hg amalgam. They exhibit 5f→6d transitions in the visible region and near-infrared emission that are highly sensitive to changes in the coordination environment.

    • Todd N. Poe
    • Harry Ramanantoanina
    • Cristian Celis-Barros
    Research
    Nature Chemistry
    Volume: 15, P: 722-728