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Showing 1–2 of 2 results
Advanced filters: Author: Cambell S. Conour Clear advanced filters

  • The activation of small molecules by organometallic complexes, as far as uranium has transformed our understanding of electronic structure and bonding. Here, the authors report a transuranic Pu(III) complex and demonstrate its differences in small molecule reactivity compared to the U(III) and Sm(III) analogs.

    • Megan Keener
    • Thayalan Rajeshkumar
    • Polly L. Arnold
    ResearchOpen Access
    Nature Communications
    P: 1-12

  • Understanding the electronic structure of the actinide series is critical for advancing the nuclear fuel cycle. Here, the authors explore a series of isostructural An(COTbig)2 (An = Th, U, Np, Pu) complexes with clam-shell geometries, where structural and electronic characterization highlights the impact of f-orbital contributions in actinide bonding.

    • Cambell S. Conour
    • Mikaela Mary F. Pyrch
    • Polly L. Arnold
    ResearchOpen Access
    Communications Chemistry
    Volume: 8, P: 1-8