Photocatalysts that can engage a range of substrates and regulate reactivity and enantioselectivity are highly desirable. Now, an enantioselective energy transfer catalysis-enabled photocyclization of acrylanilides has been developed. Reactivity and enantioselectivity are simultaneously regulated by a commercial chiral Al–salen complex upon irradiation, enabling the formation of diverse cyclic products with high levels of enantioselectivity.
- Julia Soika
- Carina Onneken
- Ryan Gilmour