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Showing 1–2 of 2 results
Advanced filters: Author: Carina Onneken Clear advanced filters
  • Photocatalysts that can engage a range of substrates and regulate reactivity and enantioselectivity are highly desirable. Now, an enantioselective energy transfer catalysis-enabled photocyclization of acrylanilides has been developed. Reactivity and enantioselectivity are simultaneously regulated by a commercial chiral Al–salen complex upon irradiation, enabling the formation of diverse cyclic products with high levels of enantioselectivity.

    • Julia Soika
    • Carina Onneken
    • Ryan Gilmour
    ResearchOpen Access
    Nature Chemistry
    Volume: 17, P: 1383-1390
  • Irradiation of chiral Al-salen complexes with violet light demonstrates efficient deracemization of cyclopropanes, enabling reactivity and enantioselectivity to be regulated simultaneously, negating the requirement for tailored catalyst–substrate recognition motifs.

    • Carina Onneken
    • Tobias Morack
    • Ryan Gilmour
    ResearchOpen Access
    Nature
    Volume: 621, P: 753-759