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Showing 1–3 of 3 results
Advanced filters: Author: Chuan-Gang Zhao Clear advanced filters

  • The development of gold catalysis is restricted by its high redox potential, and the introduction of strong oxidants to overcome this is accompanied by poor functional group compatibility. Here electrochemical oxidation is used to control gold valence changes, showing excellent compatibility with a wide range of active functional groups and bio-additives.

    • Hao Liang
    • Yilitabaier Julaiti
    • Jin Xie
    Research
    Nature Synthesis
    Volume: 2, P: 338-347

  • Aromatic tertiary amines are versatile building blocks in organic synthesis. In this article, the authors report on an iron-catalysed reaction for the decarboxylative C-N coupling from carboxylic acids and nitroarenes, leading to non-symmetric tertiary aromatic amines.

    • Shuaishuai Wang
    • Tingrui Li
    • Jin Xie
    ResearchOpen Access
    Nature Communications
    Volume: 13, P: 1-10

  • Activation of inert chemical bonds employing classical photocatalysts usually involves an outer-sphere single electron transfer mechanism. Now, an alternative inner-sphere single electron transfer pathway for the homolytic cleavage of strong C–Cl bonds using gold catalysts is reported.

    • Cheng-Long Ji
    • Jie Han
    • Jin Xie
    Research
    Nature Catalysis
    Volume: 5, P: 1098-1109