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Showing 1–5 of 5 results
Advanced filters: Author: Cyrille Costentin Clear advanced filters

  • Redox reactions related to renewable energy challenges can be mediated by molecular electrocatalysts. Intelligent design of these catalysts calls for systematic catalyst benchmarking. This Perspective presents examples of analysing catalytic Tafel plots, noting through-structure and through-space effects on the performance and mechanism. This approach is preferred to oversimplifications inherent in using volcano plots.

    • Cyrille Costentin
    • Jean-Michel Savéant
    Reviews
    Nature Reviews Chemistry
    Volume: 1, P: 1-8

  • Theoretical analysis of competing diffusion modes within electrocatalytic films is challenging. It is now shown that the competition depends on a single dimensionless parameter that contains all operational and structural experimental factors.

    • Cyrille Costentin
    • Carlo Di Giovanni
    • Cédric Tard
    Research
    Nature Materials
    Volume: 16, P: 1016-1021

  • A hybrid carbon nanotube/molecular catalyst achieves highly selective electrochemical conversion of CO to methanol via mechanistic-guided optimizations.

    • Cyrille Costentin
    News & Views
    Nature Synthesis
    Volume: 2, P: 1134-1135

  • Electrocatalytic processes involving gas molecules are generally limited by low solubility in aqueous solutions. Here water endowed with permanent microporosity by silicalite-1 nanocrystals is used to concentrate O2, allowing the measurement of the intrinsic activity of a Pt/C catalyst in the oxygen reduction reaction.

    • Agnes E. Thorarinsdottir
    • Daniel P. Erdosy
    • Daniel G. Nocera
    Research
    Nature Catalysis
    Volume: 6, P: 425-434

  • Electrochemical research often requires stringent combinations of experimental parameters that are demanding to manually locate. Here the authors report an autonomous electrochemical platform that implements an adaptive, closed-loop workflow for mechanistic investigation of molecular electrochemistry.

    • Hongyuan Sheng
    • Jingwen Sun
    • Chong Liu
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-10