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Showing 1–17 of 17 results
Advanced filters: Author: D. Chernyshov Clear advanced filters
  • Manganese-based hydrogenation catalysts are sensitive to high temperatures and may degrade under industrially relevant conditions. Here, the authors report a highly efficient manganese pincer pre-catalyst displaying high TOF values (up to 41 000 h−1) and stability (TON up to 200 000) at loadings as low as 5-200 ppm.

    • Wenjun Yang
    • Ivan Yu. Chernyshov
    • Evgeny A. Pidko
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-8
  • The mechanism underpinning the photovoltaic effect in hybrid perovskite solar cells has remained unclear. Here, Green and co-workers suggest that iodide ions in methylammonium lead iodide perovskite migrate via interstitial sites and undergo a redox reaction to form molecular iodine and free electrons.

    • J. L. Minns
    • P. Zajdel
    • M. A. Green
    ResearchOpen Access
    Nature Communications
    Volume: 8, P: 1-5
  • The mechanism of the multiple-q charge density wave phase in the antiferromagnetic kagome metal FeGe is not fully understood. Here the authors reveal dimerization-driven hexagonal charge-diffuse precursor and identify the fraction of dimerized/undimerized states as the key order parameter of the phase transition.

    • D. Subires
    • A. Kar
    • S. Blanco-Canosa
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-11
  • The mechanism of the charge density wave in kagome metals is under intense debate. Here, by using a combination of diffuse scattering and inelastic x-ray scattering, the authors show that the charge density wave transition in (Cs,Rb)V3Sb5 is of the order-disorder type.

    • D. Subires
    • A. Korshunov
    • S. Blanco-Canosa
    ResearchOpen Access
    Nature Communications
    Volume: 14, P: 1-7
  • The recently discovered charge density wave in ScV6Sn6 kagome metal is under intense debate. By using a combination of experimental and theoretical techniques, the authors point to the role of flat phonon mode softening and momentum-dependent electron-phonon coupling in the formation of the charge density wave.

    • A. Korshunov
    • H. Hu
    • S. Blanco-Canosa
    ResearchOpen Access
    Nature Communications
    Volume: 14, P: 1-8
  • Here authors investigate the effects of different metals incorporated in the structures and possible additional phases have on the CO2 uptake of pyrene-based MOFs. Results show that when additional phases are present, the pore volume is reduced and CO2 binding sites in the structure are different, leading to different adsorption properties.

    • Nency P. Domingues
    • Miriam J. Pougin
    • Berend Smit
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-12
  • Lattice anchoring, in its varied forms, has proven effective at regulating the energetics of metastable phases of polymorphic crystals. Here, the authors utilize top-down photolithography to embed a tessellating 3D interfacial network into otherwise-unstable CsPbI3 perovskite thin films and devices, stabilizing the perovskite phase.

    • Julian A. Steele
    • Tom Braeckevelt
    • Maarten B. J. Roeffaers
    ResearchOpen Access
    Nature Communications
    Volume: 13, P: 1-11
  • Functional behaviour can emerge in materials in which magnetic order is determined by the interplay of localised and itinerant magnetic interactions. Here the authors tune such magnetic order in a photovoltaic perovskite by tuning the electronic carrier concentration under visible light illumination.

    • B. Náfrádi
    • P. Szirmai
    • E. Horváth
    ResearchOpen Access
    Nature Communications
    Volume: 7, P: 1-8
  • Although antiferroelectric lead zirconate is a principal component in the most widely used piezoelectric ceramics, the nature of its antiferroelectricticity has been unclear. Here Tagantsevet al.reveal how this phenomenon arises from the softening of a single lattice mode.

    • A. K. Tagantsev
    • K. Vaideeswaran
    • N. Setter
    Research
    Nature Communications
    Volume: 4, P: 1-8
  • Disorder localizes electrons, which is usually detrimental to the onset of superconductivity. Here, Petrović et al. report a disorder-enhanced superconducting instability in quasi-one dimensional Na2-dMo6Se6and suggest that this effect may originate from an intrinsically screened Coulomb repulsion.

    • A. P. Petrović
    • D. Ansermet
    • C. Panagopoulos
    ResearchOpen Access
    Nature Communications
    Volume: 7, P: 1-10
  • Phase transitions in materials are intriguing, and can also be of practical importance. Below ∼150 K, mixed-valent iron oxide Fe4O5 has now been shown to undergo an unusual charge-ordering phase transition that involves the competing formation of iron dimers and trimers, and leads to a significant increase in electrical resistivity.

    • Sergey V. Ovsyannikov
    • Maxim Bykov
    • Leonid S. Dubrovinsky
    Research
    Nature Chemistry
    Volume: 8, P: 501-508
  • Piezoelectric materials are used for a broad range of industrial and research applications. The authors use synchrotron X-ray scattering and digital imaging correlation to investigate the microscopic mechanisms behind electromechanical strains in a lead-free piezoceramic material, which suggests an unconventional domain switching mechanism and ability to enhance the temperature range of operation by suitable doping strategies.

    • Sarangi Venkateshwarlu
    • Lalitha K. Venkataraman
    • Abhijit Pramanick
    ResearchOpen Access
    Communications Physics
    Volume: 3, P: 1-14