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Showing 1–2 of 2 results
Advanced filters: Author: Daniel J. SantaLucia Clear advanced filters
  • The synthesis, structure and reactivity of room-temperature-stable [Cp(C6F5)5]+[Sb3F16] is presented. Coordination of the cyclopentadienyl cation by [Sb3F16] or C6F6 stabilizes the antiaromatic singlet state in the solid state. Calculated hydride and fluoride ion affinities of the [Cp(C6F5)5]+ cation are higher than those of the tritylium cation [C(C6F5)3]+.

    • Yannick Schulte
    • Christoph Wölper
    • Stephan Schulz
    Research
    Nature Chemistry
    Volume: 16, P: 651-657
  • The molecular genetic landscape of leiomyosarcoma (LMS) is largely unknown. Here, the authors identify frequent DNA copy number alterations, whole-genome duplication, TP53 and RB1 inactivation, alternative telomere lengthening, and genomic imprints of defective DNA repair via homologous recombination as a potential therapeutic target in LMS patients.

    • Priya Chudasama
    • Sadaf S. Mughal
    • Stefan Fröhling
    ResearchOpen Access
    Nature Communications
    Volume: 9, P: 1-15