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Showing 1–3 of 3 results
Advanced filters: Author: De-Wei Gao Clear advanced filters

  • The formation of alkoxyl boronate complexes in cross-coupling reactions typically undergo classical transmetallation followed by reductive elimination to form C–C and C–X bonds. Here, the authors report an iridium-catalyzed asymmetric alkylation that enables the stereoselective construction of cis-cyclobutanes, employing the high ring strain of bicyclo[1.1.0]butane-derived boronate complexes to induce 1,2-alkoxy migration.

    • Xin-Yuan Zhu
    • Chong-Lei Ji
    • De-Wei Gao
    ResearchOpen Access
    Nature Communications
    Volume: 17, P: 1-11

  • The strain-release-driven reactions of bicyclo[1.1.0]butanes (BCBs) have received significant attention from chemists. Herein, the authors report an asymmetric synthesis of atropisomers featuring cis-cyclobutane boronic esters facilitated by 1,2-carbon or boron migration of ring-strained B-ate complexes, achieving high enantioselectivity.

    • Yu-Wen Sun
    • Jia-Hui Zhao
    • De-Wei Gao
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-9