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Showing 1–7 of 7 results
Advanced filters: Author: Dominik Munz Clear advanced filters

  • The isolation of secondary and primary carbon radical species is challenging, owing to their instability. Now the reduction of an acyclic bis(imino)carbene conjugate acid enables the isolation of a stable pentadienyl-type radical. In silico and in vitro probing of its properties reveal a propensity to act as a secondary carbon radical.

    • Ying Kai Loh
    • Levan Gojiashvili
    • Guy Bertrand
    Research
    Nature Synthesis
    Volume: 3, P: 727-731

  • The synthesis and isolation of a crystalline dication derived from a bis(imino)carbene through a two-electron oxidation/oxide-ion abstraction strategy is reported that bypasses the carbene radical cation, maintaining significant electrophilicity with two accessible vacant orbitals.

    • Ying Kai Loh
    • Mohand Melaimi
    • Guy Bertrand
    Research
    Nature
    Volume: 623, P: 66-70

  • Nitrenes are compounds featuring a monovalent nitrogen atom, and they are typically formed as transient intermediates in organic synthesis. They have been the subject of matrix studies for decades, but their stabilization remains challenging. Now, two independent works report the isolation of triplet arylnitrenes stabilized by a sterically encumbered substituent.

    • Dominik Munz
    News & Views
    Nature Chemistry
    Volume: 17, P: 6-7

  • Complexes of iron in high oxidation states play a pivotal role as active intermediates in numerous catalytic processes. Now, using a multimethod approach on a single molecular system, it has been shown that a stable high-valent Fe(VI) nitride can be converted to a reactive, superoxidized, heptavalent Fe(VII) nitride.

    • Martin Keilwerth
    • Weiqing Mao
    • Karsten Meyer
    ResearchOpen Access
    Nature Chemistry
    Volume: 16, P: 514-520

  • The persistence of the immune response to SARS-CoV-2 after recovery from infection is an indicator for subsequent protection against infection. Here the authors follow recovered patients and measure antibody and T cell responses and find that these two parts of the immune response may have different longevity.

    • Dominik Menges
    • Kyra D. Zens
    • Jan S. Fehr
    ResearchOpen Access
    Nature Communications
    Volume: 13, P: 1-16

  • Charge-separated organic molecules find diverse applications as functional materials. This Review describes zwitterionicity as a general design principle for ‘smart’ coordination chemistry and the activation of strong bonds.

    • Dominik Munz
    • Karsten Meyer
    Reviews
    Nature Reviews Chemistry
    Volume: 5, P: 422-439