Radical philicity — the ability of a radical to act as a nucleophile or an electrophile — is an important, yet often poorly understood, concept. In this Review, we present a qualitative method to understand and predict radical philicity by classifying the typical reactivity of more than 30 types of radicals into nucleophilic or electrophilic behaviour.
- Faeze Parsaee
- Milinda C. Senarathna
- Eric R. Welin