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Showing 1–16 of 16 results
Advanced filters: Author: Fabrice Wilhelm Clear advanced filters

  • Manipulating the physical properties of solid matter using only photons is a major challenge in materials science. Here, the authors present the photochemistry occurring in a single crystal of a Mo(III) cyanide complex which undergoes a reversible breaking and reformation of dative bonds and spin state change upon exposure to visible light.

    • Michał Magott
    • Mirosław Arczyński
    • Dawid Pinkowicz
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-10

  • Phosphorus mononitride is highly unstable under atmospheric conditions and its utility for constructing elusive P–N π-bonded motifs has remained uncertain. Here, the authors show that Na(OCP) can transfer a P atom to an electrophilic osmium nitride complex to form a metal-bound P≡N ligand.

    • Simon Edin
    • Christian Sandoval-Pauker
    • Anders Reinholdt
    ResearchOpen Access
    Nature Communications
    Volume: 16, P: 1-12

  • Ultrasmall metallic clusters receive great attention for atom-efficient catalysts. Here a metallic cluster–organic framework is synthesized and characterized; authors demonstrate its stability and catalytic proficiency, paving the way for molecular-scale metal nanoparticle interlocking.

    • Xiyue Liu
    • James N. McPherson
    • Kasper S. Pedersen
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-10

  • Iridates are known to exhibit a range of exotic electronic and magnetic behaviours but it is difficult to prepare isolated [IrO6]8− species via soft chemical routes. Here, the authors isolate the isoelectronic [IrF6]2−complex, and assess it as a model and for iridate analogues.

    • Kasper S. Pedersen
    • Jesper Bendix
    • Rodolphe Clérac
    ResearchOpen Access
    Nature Communications
    Volume: 7, P: 1-8

  • Achieving high conductivity in metal-organic solids can be challenging, due to the difficulty of obtaining a good overlap between the d-orbitals of the metal and the π-orbitals of the organic molecule. Here, the authors present two coordination solids, VCl2(pyrazine)2 and TiCl2(pyrazine)2, with remarkably different electrical conductivity. While the former is an insulator, the latter displays the highest conductivity of any octahedrally coordinated metal ions based metal-organic solid.

    • Panagiota Perlepe
    • Itziar Oyarzabal
    • Rodolphe Clérac
    ResearchOpen Access
    Nature Communications
    Volume: 13, P: 1-7

  • Trace element ratios (strontium/calcium) in teeth of Pleistocene Homo erectus and fossil orangutans (Pongo sp.) reveal different dietary strategies and contrasting adaptations to seasonal food resources. H. erectus but not Pongo sp. was able to buffer against seasonal food oscillations by exploiting more varied food sources.

    • Jülide Kubat
    • Alessia Nava
    • Wolfgang Müller
    Research
    Nature Ecology & Evolution
    Volume: 7, P: 279-289

  • Layered coordination polymers are attractive for the preparation of advanced 2D materials but they are typically non-magnetic insulators. Now such a layered network, CrCl2(pyrazine)2, has been prepared that comprises a paramagnetic metal ion and a redox-active ligand. The material exhibits both magnetism — with a ferrimagnetic ground state — and high electrical conductivity.

    • Kasper S. Pedersen
    • Panagiota Perlepe
    • Rodolphe Clérac
    Research
    Nature Chemistry
    Volume: 10, P: 1056-1061

  • Weak magneto-chiral dichroic effects may explain why biomolecules all have the same chirality, but they are notoriously difficult to observe. Using hard X-rays, strong magneto-chiral dichroism has now been observed in a paramagnetic molecular helix.

    • Roberta Sessoli
    • Marie-Emmanuelle Boulon
    • Andrei Rogalev
    Research
    Nature Physics
    Volume: 11, P: 69-74

  • Here, large-scale genome-wide association studies were carried out with the naturally occurring inbred lines of Arabidopsis thaliana, which can be genotyped once and phenotyped repeatedly. The results range from significant associations, usually corresponding to single genes, to findings that are more difficult to interpret, because confounding by complex genetics and population structure makes it hard to distinguish true associations from false.

    • Susanna Atwell
    • Yu S. Huang
    • Magnus Nordborg
    Research
    Nature
    Volume: 465, P: 627-631

  • UTe2 is a strong candidate for spin-triplet superconductivity; however, to fully understand its superconducting properties a more complete understanding of its general electronic structure is needed. Here, the authors perform two types of X-ray spectroscopy to investigate the 5 f electronic states of the uranium atom, finding unusual features for the pressure dependence of the 5 f electron count.

    • Fabrice Wilhelm
    • Jean-Pierre Sanchez
    • Andrei Rogalev
    ResearchOpen Access
    Communications Physics
    Volume: 6, P: 1-7

  • This Perspective describes the development and capabilities of SciPy 1.0, an open source scientific computing library for the Python programming language.

    • Pauli Virtanen
    • Ralf Gommers
    • Yoshiki Vázquez-Baeza
    ReviewsOpen Access
    Nature Methods
    Volume: 17, P: 261-272