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Showing 1–5 of 5 results
Advanced filters: Author: Felix J. Rizzuto Clear advanced filters
  • Nature uses out-of-equilibrium systems to control hierarchical assembly. Now, a dissipative chemical system has been shown to slowly release monomer DNA strands from a high-energy reservoir, regulating self-assembly by switching the mechanism of supramolecular polymerization at the single-molecule level. This process heals fibre defects, converting branched, heterogeneous networks into nanocable superstructures.

    • Felix J. Rizzuto
    • Casey M. Platnich
    • Hanadi F. Sleiman
    Research
    Nature Chemistry
    Volume: 13, P: 843-849
  • The combination of dynamic, energy driven folding and growth with structural stiffness and length control is difficult to achieve in synthetic polymer self-assembly. Here the authors show that highly charged, monodisperse DNA oligomers assemble via seeded growth into length-controlled supramolecular fibers during heating.

    • Michael D. Dore
    • Muhammad Ghufran Rafique
    • Hanadi F. Sleiman
    ResearchOpen Access
    Nature Communications
    Volume: 15, P: 1-13
  • An interconverting system of three distinct stereoisomers of a cuboctahedral CoII-based cage is able to regulate the binding affinities of large anionic guests. Through cooperative templation with fullerene guests, the cage converts into a desymmetrized cage that in turn exhibits positive cooperativity in binding of an icosahedral anion; this interaction is anti-cooperative in the fullerene-free parent.

    • Felix J. Rizzuto
    • Jonathan R. Nitschke
    Research
    Nature Chemistry
    Volume: 9, P: 903-908
  • Selective binding of multiple guests within cages could lead to new applications in catalysis and sensing. This Review discusses the design of synthetic cages with the aim of developing and controlling guest–guest chemistry.

    • Felix J. Rizzuto
    • Larissa K. S. von Krbek
    • Jonathan R. Nitschke
    Reviews
    Nature Reviews Chemistry
    Volume: 3, P: 204-222